| Bi- and tridentate coordination behaviour of a novel bis(phosphinimino)methanide ligand |
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| Intramolecular dearomative 1,4-addition of silyl and germyl radicals to a phenyl moiety |
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| Quo Vadis CO<inf>2</inf> Activation: Catalytic Reduction of CO<inf>2</inf> to Methanol Using Aluminum and Gallium/Carbon-based Ambiphiles |
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| The Solvent-free Lithium Alanate {Li[t-Bu<inf>2</inf>AlH<inf>2</inf>]}<inf>n</inf>: A New Product Obtained from a Long-Known Reaction |
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| [GeRu<inf>6</inf>(CO)<inf>18</inf>HI]: A Germanium-Centered Ruthenium Carbonyl Cluster with Aromatic Ring Current |
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| Visible-Light Activation of Diorganyl Bis(pyridylimino) Isoindolide Aluminum(III) Complexes and Their Organometallic Radical Reactivity |
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| How to Deal with Charge in the Ranking of Lewis Acidity: Critical Evaluation of an Extensive Set of Cationic Lewis Acids |
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| Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements |
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| Aktivierung von Diorganyl‐bis(pyridylimino)isoindolid‐Aluminiumkomplexen mit sichtbarem Licht und deren organometallische Radikalreaktivität |
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| A crystalline aluminum/carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media |
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| Non-Palindromic C∧C∧P Platinum and Palladium Pincer Complexes Showing Intense Phosphorescence via Direct Spin-Forbidden S0 → T1 Excitation |
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| Heteroatom-Based Diradical(oid)s |
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| Synthesis, Crystal Structures, and Ion Pairing of κ6N Complexes with Rare‐Earth Elements in the Solid State and in Solution |
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| Synthesis and Characterization of Bis(pyridylimino)isoindolide Alkali Metal Complexes in Three Redox States |
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| Bor‐Zentrierte Lewis‐Supersäuren durch Redoxaktive Liganden: Anwendung in der C‐F‐ und S‐F‐Bindungsaktivierung |
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| Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation |
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| Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids |
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| A neutral, acyclic, borataalkene-like ligand for group 11 metals: L- and Z-type ligands side by side |
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| Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives |
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| Cyclopenta-fused polyaromatic hydrocarbons: synthesis and characterisation of a stable, carbon-centred helical radical |
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| Heterobimetallic Gold/Ruthenium Complexes Synthesized via Post‐functionalization and Applied in Dual Photoredox Gold Catalysis |
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| Asymmetrically Difunctionalized 1,1′‐Ferrocenyl Metalloligands and Their Transition Metal Complexes |
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| Accessing Cationic α‐Silylated and α‐Germylated Phosphorus Ylides |
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| Cover Feature: Accessing Cationic α‐Silylated and α‐Germylated Phosphorus Ylides (Chem. Eur. J. 1/2022) |
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| Non-palindromic (C^C^D) gold(iii) pincer complexes are not accessible by intramolecular oxidative addition of biphenylenes - an experimental and quantum chemical study |
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| Cover Feature: Multistimuli‐Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches (Chem. Eur. J. 61/2021) |
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| Multistimuli-Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches |
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| NON‐Ligated N‐Heterocyclic Tetrylenes |
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| Completing the triad: Synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals |
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| Synthetic access to a phosphorescent non-palindromic pincer complex of palladium by a double oxidative addition-comproportionation sequence |
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| Imidazolyl Alanes – Synthesis, Structures, and Reactivity Studies |
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| Synthesis of New Donor-Substituted Biphenyls: Pre-ligands for Highly Luminescent Gold(III) Pincer Complexes |
|
| Cover Feature: Structural Characterization and Lifetimes of Triple‐Stranded Helical Coinage Metal Complexes: Synthesis, Spectroscopy and Quantum Chemical Calculations (Chem. Eur. J. 47/2020) |
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| Structural Characterization and Lifetimes of Triple‐Stranded Helical Coinage Metal Complexes: Synthesis, Spectroscopy and Quantum Chemical Calculations |
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| Reactivity of a Sterically Unencumbered ?-Borylated Phosphorus Ylide towards Small Molecules |
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| The dynamic nature of Cu sites in Cu-SSZ-13 and the origin of the seagull NOx conversion profile during NH3-SCR |
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| Tetranuclear [FeII2FeIII2]2+ molecular switches: [FeII(bik)2(N–)2] spin-crossover complexes containing [FeIII(Tp)(CN)3]– metalloligands as N-donor |
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| Rhodium(I) and Iridium(I) Complexes of Ferrocenyl-Functionalized Amidinates and Bis(amidinates): kappa N-2-Coordination Versus Ferrocenyl Ortho-Metalation |
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| Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue |
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| Star-shaped triarylamines – One-step metal-free synthesis and optoelectronic properties |
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| Redox-responsive phosphonite gold complexes in hydroamination catalysis |
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| Phosphine-functionalised tris(pyrazolyl)methane ligands and their mono- and heterobimetallic complexes |
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| An Anionic Aluminium Nucleophile |
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| Rhodium(I) Complexes of N-Aryl-Substituted Mono- and Bis(amidinates) Derived from Their Alkali Metal Salts |
|
| Congratulations to Werner Uhl |
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| Frontispiece: α‐Borylated Phosphorus Ylides (α‐BCPs): Electronic Frustration within a C−B π‐Bond Arising from the Competition for a Lone Pair of Electrons |
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| α‐Borylated Phosphorus Ylides (α‐BCPs): Electronic Frustration within a C−B π‐Bond Arising from the Competition for a Lone Pair of Electrons |
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| A Metal-Containing N-Heterocyclic Germylene Based on an Oxalamidine Framework |
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| Solution and Solid-State Study of the Spin-Crossover [Fe-II(R-bik)(3)](BF4)(2) Complexes (R = Me, Et, Vinyl) |
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| Ein anionisches Aluminium‐Nukleophil |
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| Cover Feature: Rhodium(I) Complexes of N‐Aryl‐Substituted Mono‐ and Bis(amidinates) Derived from Their Alkali Metal Salts (Eur. J. Inorg. Chem. 26/2018) |
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| Synthesis, Characterisation and Reactions of Truly Cationic Ni<sup>I</sup>-Phosphine Complexes |
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| Palladium complexes of ferrocene-based phosphine ligands as redox-switchable catalysts in Buchwald-Hartwig cross-coupling reactions |
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| Multidentate silyl ligands in transition metal chemistry |
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| Metal Complexes of a Redox-Active [1]Phosphaferrocenophane: Structures, Electrochemistry and Redox-Induced Catalysis |
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| A Redox-Switchable Germylene and its Ligating Properties in Selected Transition Metal Complexes |
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| A combined experimental and quantum chemical study on thallium(I) tris(pyrazolyl)methanide |
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| Molecular Spin Crossover in Slow Motion: Light-Induced Spin-State Transitions in Trigonal Prismatic Iron(II) Complexes |
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| A Boron-Fluorinated Tris(pyrazolyl)borate Ligand ((F)Tp*) and Its Mono- and Dinuclear Copper Complexes [Cu((F)Tp*)(2)] and [Cu-2((F)Tp*)(2)]: Synthesis, Structures, and DFT Calculations |
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| A Dinuclear Gold(I) Bis(Carbene) Complex Based on a Ditopic Cyclic (Aryl)(Amino)Carbene Framework |
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| Differential Many-Body Cooperativity in Electronic Spectra of Oligonuclear Transition-Metal Complexes |
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| Aluminium Diphosphamethanides: Hidden Frustrated Lewis Pairs |
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| K subset of{[Fe-II(Tp)(CN)(3)](4)[Co-III((pz)Tp)](3)[Co-II((pz)Tp)]}: a neutral soluble model complex of photomagnetic Prussian blue analogues |
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| Time-resolved IR spectroscopy of a trinuclear palladium complex in solution |
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| Crystalline cyclic (alkyl)(amino)carbene-tetrafluoropyridyl radical |
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| Diaryldichalcogenide radical cations |
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| Tris(3,5-dimethylpyrazolyl)methane-Based Heterobimetallic Complexes that Contain Zn and CdTransition-Metal Bonds: Synthesis, Structures, and Quantum Chemical Calculations |
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| In-depth exploration of the photophysics of a trinuclear palladium complex |
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| A metallacyclic alkyl-amido carbene complex (MCAAC) |
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| Coinage metal complexes of tris(pyrazolyl)methanide-based redox-active metalloligands |
|
| Die Ästhetik der [1.1.1]Propellane |
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| From MgBr via single-electron transfer (SET) to a paramagnetic Mg(II) compound and back to Mg(I): [MgBr(L-1)(center dot)](2) and [K(thf)(3)](2)[Mg-2(L-1)(2)], L-1 = RN=C(Me)C(Me)=NR, R=2,6-diisopropylphenyl |
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| The aesthetics of the [1.1.1] propellanes |
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| Mono- vs. dinuclear gold-catalyzed intermolecular hydroamidation |
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| Synthesis and structures of 1,3-bis(organochalcogenyl) distannatrisilabicyclo[1.1.1]pentanes |
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| Development of a metal-ion-mediated base pair for electron transfer in DNA |
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| Exploring the solution behavior of f-element coordination compounds: A case study on some trivalent rare earth and plutonium complexes |
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| Heterobimetallic cuprates consisting of a redox-switchable, silicon-based metalloligand: Synthesis, structures, and electronic properties |
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| Investigations on the steric accessibility of the carbanionic moiety in zwitterionic magnesium tris(pyrazolyl)methanide complexes. Synthesis and characterisation of Bi- and trimetallic complexes |
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| Homoleptic Tetrakis(silyl) Complexes of Pd-0 and Pt-0 Featuring Metal-Centred Heterocubane Structures: Evidence for the Existence of the Corresponding Mononuclear Pd-I and Pt-I Complexes |
|
| On the Solution Behaviour of Benzyllithium.(-)-Sparteine Adducts and Related Lithium Organyls - A Case Study on Applying Li-7,N-15{H-1}HMQC and Further NMR Methods, Including Some Investigation into Asymmetric Synthesis |
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| Heteroleptic [<i>n</i>]Chromoarenophanes:<i>ansa</i>Complexes Derived from [Cr(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>)] |
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| Palladium-containing polymers via a combination of RAFT and triazole chemistry |
|
| [2.2] Paracyclophane derived bisphosphines for the activation of hydrogen by FLPs: Application in domino hydrosilylation/hydrogenation of enones |
|
| Alkynyl-functionalised and linked bicyclo[1.1.1]pentanes of group 14 |
|
| 1H,89Y HMQC and Further NMR Spectroscopic and X-ray Diffraction Investigations on Yttrium-Containing Complexes Exhibiting Various Nuclearities |
|
| Sodium and potassium salts of mono- and dianionic ?-iminopyridines |
|
| New perspectives for "non-classical" molecules: Heavy [1.1.1]propellanes of group 14 |
|
| Tuning the gap: Electronic properties and radical-type reactivities of heteronuclear [1.1.1]propellanes of heavier group 14 elements |
|
| Experimental charge density distribution of non-coordinating sp(3) carbanions in [Mg{(pz*)(3)C}(2)] |
|
| A triangulopalladium cluster consisting of [small mu ]3-capping silyl ligands |
|
| Copper complexes of tripodal κ6N-donor ligands: A structural, EPR spectroscopic and electrochemical study |
|
| Synthesis of a pentasilapropellane. Exploring the nature of a stretched silicon-silicon bond in a nonclassical molecule |
|
| Transfer of a Disilenyl Moiety to Aromatic Substrates and Lateral Functional Group Transformation in Aryl Disilenes |
|
| Radical-type reactivity of metalla[1.1.1]propellanes of group 14: Syntheses, structures, and reduction chemistry of transition metal-terminated bicyclo[1.1.1]pentastannanes |
|
| The reduction chemistry of ferrocenylborole |
|
| Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methane and Zwitterionic Tris(pyrazolyl)methanide Compounds |
|
| Silver-Ethene Complexes [Ag(eta(2)-C2H4)(n)][Al(ORF)(4)] with n=1, 2, 3 (R-F = Fluorine-Substituted Group) |
|
| Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate kappa Si-1/kappa N-3-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand Si(3,5-Me(2)pz)(3) (-) ((Me)Tpsd) |
|
| Neutral and cationic main group element cages of germanium(ii) with pyrazolyl ligands: solid state structures, DFT calculations and advanced solution NMR investigations |
|
| Li-7,N-15 heteronuclear multiple quantum shift correlation-a fast and reliable 2D NMR method on natural abundant nuclei |
|
| Syntheses, structures and electronic properties of zwitterionic iron(II) and cobalt(II) complexes featuring ambidentate tris(pyrazolyl)methanide Ligands |
|
| Pentagerma[1.1.1]propellane: A combined experimental and quantum chemical study on the nature of the interactions between the bridgehead atoms |
|
| Snapshots of the Al-Al sigma-Bond Formation Starting from {AlR2} Units: Experimental and Computational Observations |
|
| Synthesis, Crystal Structures and Redox Properties of Mixed-Sandwich Complexes of Ruthenium(II) with Cyclopentadienyl and Tris(pyrazolyl)methane Ligands |
|
| Synthesis, crystal structure, EPR and DFT studies, and redox properties of [2]tetramethyldisilacobaltocenophane |
|
| Multidentate ligand systems featuring dual functionality |
|
| Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring “Free” Pyramidal Carbanions |
|
| Stretching bonds in main group element compounds-Borderlines between biradicals and closed-shell species |
|
| Cationic Main Group Element Cages of Germanium(II) and Tin(II) Consisting of 3,5-Di(t-butyl) Substituted Pyrazolyl Ligands in the Bridging Position |
|
| Hydrogallation of Trimethylsilylethynylbenzenes: Generation of Potential Di- and Tripodal Chelating Lewis Acids |
|
| High-yield ruthenium-catalyzed Friedel-Crafts-type allylation reactions using dicationic RuIV catalysts |
|
| To boldly pass the metal-metal quadruple bond |
|
| Coinage metal complexes of tris(pyrazolyl)methanide [C(3,5-Me<sub>2</sub>pz)<sub>3</sub>]<sup>−</sup>: κ<sup>3</sup>-coordination vs. backbone functionalisation |
|
| Two Different Products Observed in the Reaction of a Bis(germylene) with Molybdenum Hydride [Mo(H)Cp(CO)3] |
|
| Synthesis of a Rhodaazacyclopropane and Characterization of Its Radical Cation by EPR Spectroscopy |
|
| Catalytic allylic alkylation and allylic phenolation reactions with ruthenium complexes. Solid-state structures of a model catalytic DMF intermediate, Ru(Cp*)(Cl)(eta(3)-C3H5)(DMF) (PF6), and a new tetranuclear salt, Ru(Cp){Ru(Cp)(eta(6)-p-CH3C6H4CN)}(3) (PF6)(4) |
|
| Chiral rhodium(I) and iridium(I) amino-olefin complexes: pK(a), N-H bond dissociation energy, and catalytic transfer hydrogenation |
|
| Copper(I) Chloride Cluster Complexes with Pentaphenyl-Cyclopentaphosphane as Ligand |
|
| Diamido Rhodates(1−) |
|
| Heterolytic Splitting of Hydrogen with Rhodium(I) Amides |
|
| NMR, PGSE diffusion, and X-ray diffraction studies of lithium and potassium salts derived from diphenylphosphino(o-cyanophenyl)aniline and their crown ether complexes |
|
| Comparative Studies of Substitution Reactions of Rhenium(I) Dicarbonyl−Nitrosyl and Tricarbonyl Complexes in Aqueous Media |
|
| Ruthenium-catalyzed allylic alkylation reactions: Carbonate-based catalysts and intermediates |
|
| Chiral Olefins as Steering Ligands: Syntheses of <i>C</i><sub>1</sub>-Symmetric Dibenzo[<i>a</i>,<i>e</i>]cyclooctenes (<sup>R</sup>dbcot) |
|
| New Insight into Hydrogallation Reactions: Facile Synthesis of a Gallium-Bridged [3,3,3]-Cyclophane |
|
| Li-7, P-31, and H-1 pulsed gradient spin-echo (PGSE) diffusion NMR spectroscopy and ion pairing: On the temperature dependence of the ion pairing in Li(CPh3), fluorenyllithium, and Li N(SiMe3)(2) amongst other salts |
|
| Distannenes Turned Inside Out: Bis(stannylenes) with an Unusual Structural Motif |
|
| Olefins as steering ligands for homogeneously catalyzed hydrogenations |
|
| A monomeric organolithium compound containing a free pyramidal carbanion in solution and in the solid state |
|
| Amine olefin rhodium(I) complexes: pK(a) and NH bond strength |
|
| Two different structural motifs observed for dimeric dialkylaluminum and dialkylgallium alkynides [R2E-C C-C6H5](2) |
|
| Elemental Sulfur and Sulfur-Rich Compounds, Vols. I and II. (Series: Topics in Current Chemistry, Vols. 230, 231.). Edited by Ralf Steudel. |
|
| Stereochemical Control of the Redox Potential of Tetracoordinate Rhodium Complexes |
|
| X-ray Diffraction and NMR Studies on a Series of Binap-Based Ru(II) Hydroxyphosphine π-Arene Complexes |
|
| Thermodynamic and Kinetic Data for Adduct Formation,cis–trans Isomerization and Redox Reactions of ML4 Complexes: A Case study with Rhodium– and Iridium–tropp Complexes in d8, d9 and d10 Valence Electron Configurations (tropp= Dibenzotropylidene Phosphanes) |
|
| Functionalized borazines as precursors for new silica gels |
|
| TROPDAD: A New Ligand for the Synthesis of Water-Stable Paramagnetic[16+1]-Electron Rhodium and Iridium Complexes |
|
| Reactions of Carbaalanes with HBF<sub>4</sub> and HCl: A μ<sub>3</sub>-Bridging Fluorine Atom in (AlEt)<sub>7</sub>(CCHPh)<sub>2</sub>(CCH<sub>2</sub>Ph)<sub>3</sub>(μ<sub>3</sub>-F) versus a Terminal Chlorine Atom in (AlMe)<sub>7</sub>(AlCl)(CCH<sub>2</sub>Ph)<sub>5</sub>H |
|
| New Carbaalanes − (AlMe)8(CCH2Me)5(C≡C−Me) and the THF Adduct (AlMe)8(CCH2Me)5H·2THF |
|
| The hydroalumination of diethynes with di(tert-butyl)aluminium hydride: A facile method for the synthesis of organometallic dialuminium compounds |
|
| New carbaalanes containing clusters of aluminum and carbon atoms: (AlEt)(8)(CCH2C6H5)(5)H, (AlMe)(8)(CCH2C6H5)(5)(C C-C6H5), and (AlMe)(7)(CCH2C H-3)(4)H-2. Quantum chemical characterization |
|
| New Carbaalanes Containing Clusters of Aluminum and Carbon Atoms: (AlEt)<sub>8</sub>(CCH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)<sub>5</sub>H, (AlMe)<sub>8</sub>(CCH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)<sub>5</sub>(C⋮C-C<sub>6</sub>H<sub>5</sub>), and (AlMe)<sub>7</sub>(CCH<sub>2</sub>CH<sub>3</sub>)<sub>4</sub>H<sub>2</sub>. Quantum Chemical Characterization |
|
| Two New Carbaalanes: Compounds with an Al7C5 and a [B11H11]2− Analogous Al7C4 Cluster |
|
| Aluminium Atoms at High Connectivity Sites in Polyhedral Polyborane Analogous Clusters: From Aluminaboranes to Carbaalanes |
|
| Pentacarba-arachno-tridecaalane (AlMe)8(CCH2Ph)5H with an Al8C5 Skeleton—The First Polyhedral Carbaalane |
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