| Molecular Dihydrogen Activation by (C<inf>5</inf>Me<inf>5</inf>)M/N (M=Rh, Ir) Transition Metal Frustrated Lewis Pairs: Reversible Proton Migration to, and Proton Abstraction from, the C<inf>5</inf>Me<inf>5</inf> Ligand |
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| Dynamic Configuration on a Chiral-at-Rhodium Catalyst Featuring a Flexible Tetradentate Ligand |
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| Rhodium and Iridium Complexes of Lutidine-Based NHC/Amino Pincer Ligands: From Monodentate to Tetradentate Coordination Enabled by C-H Activation |
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| Reactivity of Ir(i)-aminophosphane platforms towards oxidants |
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| Synthesis of Ir Catalysts Featuring Amide-functionalized NHC Ligands and Survey of their Activity on Formic Acid Dehydrogenation |
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| Cobalt-catalysed nucleophilic fluorination in organic carbonates |
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| β-(Z)-Selective alkyne hydrosilylation by a N,O-functionalized NHC-based rhodium(i) catalyst |
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| Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts |
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| Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes |
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| Well-Stabilized but Strained Frustrated Lewis Pairs Based on Rh/N and Ir/N Couples |
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| Rhodium-NHC-Catalyzed gem-Specific O-Selective Hydropyridonation of Terminal Alkynes |
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| Synthesis and reactivity of an iridium complex based on a tridentate aminophosphano ligand |
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| Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights |
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| Cyclometalated iridium complexes based on monodentate aminophosphanes |
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| N-Methylation of Amines with Methanol Catalyzed by Iridium(I) Complexes Bearing an N,O-Functionalized NHC Ligand |
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| Activation of H-H, HO-H, C(sp2)-H, C(sp3)-H, and RO-H Bonds by Transition-Metal Frustrated Lewis Pairs Based on M/N (M = Rh, Ir) Couples |
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| Iridium(i) complexes bearing hemilabile coumarin-functionalised N-heterocyclic carbene ligands with application as alkyne hydrosilylation catalysts |
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| A simple and high-yield route to iridium, rhodium, osmium and ruthenium: Nido -6-metalladecaborane compounds |
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| Impact of Green Cosolvents on the Catalytic Dehydrogenation of Formic Acid: The Case of Iridium Catalysts Bearing NHC-phosphane Ligands |
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| Variation on the π-Acceptor Ligand within a RhI−N-Heterocyclic Carbene Framework: Divergent Catalytic Outcomes for Phenylacetylene-Methanol Transformations |
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| Preparation of Butadienylpyridines by Iridium-NHC-Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement |
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| Metal-Ligand Cooperative Proton Transfer as an Efficient Trigger for Rhodium-NHC-Pyridonato Catalyzed gem-Specific Alkyne Dimerization |
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| Iridium catalysts featuring amine-containing ligands for the dehydrogenation of formic acid |
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| EffectiveN-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach toN-methyl amines |
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| Ligand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange |
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| Hybrid catalysts comprised of graphene modified with rhodium-based N-heterocyclic carbenes for alkyne hydrosilylation |
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| β-(Z) Selectivity Control by Cyclometalated Rhodium(III)-Triazolylidene Homogeneous and Heterogeneous Terminal Alkyne Hydrosilylation Catalysts |
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| Rhodium(I)-NHC Complexes Bearing Bidentate Bis-Heteroatomic Acidato Ligands as gem-Selective Catalysts for Alkyne Dimerization |
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| Mechanism of the Alkylation of Indoles with Nitrostyrenes Catalyzed by Chiral-at-Metal Complexes |
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| Reversible Activation of Water by an Air- and Moisture-Stable Frustrated Rhodium Nitrogen Lewis Pair |
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| Hydride-Rhodium(III)- N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C-H Activation |
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| Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates |
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| Rhodium- N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles |
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| Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity |
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| Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N -heterocyclic carbene) Zwitterionic Iridium(I) Compound |
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| Metal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands |
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| Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands |
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| A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: The key role of an N-heterocyclic olefin |
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| Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(II) complexes |
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| Synthesis and catalytic activity of new, water-soluble mono- and dinuclear ruthenium(II) complexes containing 1,3,5-triaza-7-phosphaadamantane: Study of the effect of the visible light |
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| Divergent reactivity of 2-vinylpyridine and 1-vinylpyrazole in rhodium-phosphine systems: C-H activation and dinuclear chemistry |
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| Pd(II) complexes of monodentate deoxycholic acid derived binaphthyl diamido phosphites as chiral catalysts in the asymmetric Suzuki-Miyaura cross-coupling |
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| Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters |
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| The Stepwise Reaction of Rhodium and Iridium Complexes of Formula [MCl2(κ4C,N,N′,P−L)] with Silver Cations: A Case of trans-Influence and Chiral Self-Recognition |
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| A well-defined NHC-Ir(III) catalyst for the silylation of aromatic C-H bonds: Substrate survey and mechanistic insights |
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| Stereospecific control of the metal-centred chirality of rhodium(III) and iridium(III) complexes bearing tetradentate CNN′P ligands |
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| En route to phosphonato iridium(i) complexes: The decisive effect of an intramolecular hydrogen bond |
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| Postsynthetic modifications of [2,2,2-(H)(PPh3)2-: Closo -2,1-RhSB8H8] with Lewis bases: Cluster modular tuning |
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| Temperature Dual Enantioselective Control in a Rhodium-Catalyzed Michael-Type Friedel–Crafts Reaction: A Mechanistic Explanation |
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| Intramolecular C-H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes |
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| Rhodium(I)-N-heterocyclic carbene catalyst for selective coupling of N-vinylpyrazoles with alkynes via C-H activation |
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| Intramolecular C-H oxidative addition to iridium(I) in complexes containing a N,N′-diphosphanosilanediamine ligand |
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| Synthesis, spectroscopy and electrochemistry of new 4-(4-acetyl-5- substituted-4, 5-dihydro-1, 3,4-oxodiazol-2-yl)methoxy)-2H-chromen-2-ones as a novel class of potential antibacterial and antioxidant derivatives |
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| Comparative study of [RuClCp(HdmoPTA-kappaP)(PPh3)][CF 3SO3] and the heterobimetallic complexes [RuClCp(PPh 3)-mu-dmoPTA-1kappaP:2(kappa)2N,N’-M(acac- (kappa2O,O’)2] (M = Co, Ni, Zn; DmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane) |
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| Reactivity of novel N, N′-diphosphino-silanediamine-based rhodium(I) derivatives |
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| Rhodium(III)-catalyzed dimerization of aldehydes to esters |
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| Synthesis and reactivity of the novel hydride derivative RhHCl(TIMP 3) (HTIMP3 = tris[1-(diphenylphosphino)-3-methyl-1H-indol- 2-yl]methane) |
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| Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds |
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| Stabilization of the hydroperoxido ligand: A 1κO,2κO′ dimetallic coordination mode |
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| Intervalent bis(μ-aziridinato)MII-MI complexes (M = Rh, Ir): Delocalized metallo-radicals or delocalized aminyl radicals? |
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| Formation of a bridging-imido d6 rhodium compound by nitrene capture. Insertion and cycloaddition reactions |
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| An unprecedented iridium(III) catalyst for stereoselective dimerisation of terminal alkynes |
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| Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework |
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| Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins |
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| Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands |
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| The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV) |
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| Unsymmetrically substituted dimethyldiaminosilanes as ligands towards zirconium(IV) |
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| Structure and protonation of the bis-ethylene adduct [Pt(μ-PBu 2t)(η2-CH2=CH2)] 2. Pt-H-P agostic interaction and proton scrambling |
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| Synthesis of amino- and amido-aluminium derivatives and investigation of their dynamics in solution |
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| Synthesis and characterisation of novel zirconium(IV) derivatives containing the bis-amido ligand SiMe2(NRR′)2 |
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| Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II) |
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| Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines |
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| Aminolysis of the Si-Cl bond and ligand exchange reaction between silicon amido derivatives and SiCl4: Synthetic applications and kinetic investigations |
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| 1,10-Phenanthroline-5,6-dione as a building block for the synthesis of homo- and heterometallic complexes |
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| Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF3COO)2(THF)2]n |
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| Synthesis and characterization of mono- and bi-metallic derivatives of groups 4 and 5 with 2,5-dimethoxy-1,4-benzoquinone |
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| Synproportionation reactions between copper(II) trihalogenoacetates Cu(CX3CO2)2, X = F, Cl or Br, and copper in the presence of carbon monoxide |
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| Co-ordination properties of 1,10-phenanthroline-5,6-dione towards group 4 and 5 metals in low and high oxidation states |
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