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Introducing the Author’s Corner
Bimolecular Reductive Elimination of Ethane from Pyridine(diimine) Iron Methyl Complexes: Mechanism, Electronic Structure, and Entry into [2+2] Cycloaddition Catalysis
Kinetic and thermodynamic control of C(sp 2 )–H activation enables site-selective borylation
A butadiene-derived semicrystalline polyolefin with two-tiered chemical recyclability
Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists**
Iridium-Catalyzed Hydrogenation of a Phenoxy Radical to the Phenol: Overcoming Catalyst Deactivation with Visible Light Irradiation
Quinoline Pyridine(Imine) Iron Complexes as Catalysts for the 1,4-Hydrovinylation of 1,3-Dienes
Arene Insertion with Pincer-Supported Molybdenum-Hydrides: Determination of Site Selectivity, Relative Rates, and Arene Complex Formation
Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling
CS-Symmetric Pyridine(diimine) Iron Methyl Complexes for Catalytic [2+2] Cycloaddition and Hydrovinylation: Metallacycle Geometry Determines Selectivity
C(sp3)–C(sp2) Reductive Elimination versus β-Hydride Elimination from Cobalt(III) Intermediates in Catalytic C–H Functionalization
Asymmetric Hydrogenation of Indazole-Containing Enamides Relevant to the Synthesis of Zavegepant Using Neutral and Cationic Cobalt Precatalysts
Exploring the Effect of Pincer Rigidity on Oxidative Addition Reactions with Cobalt(I) Complexes
Collaboration as a Key to Advance Capabilities for Earth-Abundant Metal Catalysis
Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures
Iron-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Using an Alkoxide Base
Scoping Out 2023
Identification of Cyclohexadienyl Hydrides as Intermediates in Molybdenum‐Catalyzed Arene Hydrogenation
Catalytic N–H Bond Formation Promoted by a Ruthenium Hydride Complex Bearing a Redox-Active Pyrimidine-Imine Ligand
Alcohol Synthesis by Cobalt-Catalyzed Visible-Light-Driven Reductive Hydroformylation
C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles
Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts
Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects
Nickel-Catalyzed Dimerization of Di- and Trisubstituted Olefins
C(sp2)–H Activation with Bis(silylene)pyridine Cobalt(III) Complexes: Catalytic Hydrogen Isotope Exchange of Sterically Hindered C–H Bonds
Pioneers and Influencers in Organometallic Chemistry: A Profile of Dr. Barbara Burger
Molybdenum-Catalyzed Asymmetric Hydrogenation of Fused Arenes and Heteroarenes
Development of Cobalt Catalysts for the meta-Selective C(sp2)–H Borylation of Fluorinated Arenes
Cationic Bis(phosphine) Cobalt(I) Arene Complexes as Precatalysts for the Asymmetric Synthesis of Sitagliptin
Ammonia synthesis by photocatalytic hydrogenation of a N2-derived molybdenum nitride
Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization
(PNP)Cobalt-Catalyzed Olefination of Diazoalkanes
Making 2022 Picture Perfect
Visible-Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates, and Catalyst Improvements
Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands
Green Chemistry: A Framework for a Sustainable Future
40 Years of Organometallics
Well-Defined Cationic Cobalt(I) Precatalyst for Olefin-Alkyne [2 + 2] Cycloaddition and Olefin-Diene Hydrovinylation Reactions: Experimental Evidence for Metallacycle Intermediates
Green Chemistry: A Framework for a Sustainable Future
Synthesis, Electronic Structure, and Reactivity of a Planar Four-Coordinate, Cobalt–Imido Complex
Effect of Pincer Methylation on the Selectivity and Activity in (PNP)Cobalt-Catalyzed C(sp2)-H Borylation
Catalyst Design Principles Enabling Intermolecular Alkene-Diene [2+2] Cycloaddition and Depolymerization Reactions
Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen
Ligand substitution and electronic structure studies of bis(Phosphine)cobalt cyclooctadiene precatalysts for alkene hydrogenation
Green Chemistry: A Framework for a Sustainable Future
Green chemistry: A framework for a sustainable future
Green Chemistry: A Framework for a Sustainable Future
Green chemistry: A framework for a sustainable future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Green Chemistry: A Framework for a Sustainable Future
Oxidative Addition of Aryl and Alkyl Halides to a Reduced Iron Pincer Complex
Synthesis and Asymmetric Alkene Hydrogenation Activity of C2-Symmetric Enantioenriched Pyridine Dicarbene Iron Dialkyl Complexes
A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes
Pioneers and Influencers: A Profile of Dr. Kenrick Lewis
Iron-catalysed synthesis and chemical recycling of telechelic 1,3-enchained oligocyclobutanes
Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenation: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways
Iron-Catalyzed Vinylsilane Dimerization and Cross-Cycloadditions with 1,3-Dienes: Probing the Origins of Chemo- and Regioselectivity
Looking Forward to 2021: The Fabulous Forties!
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
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Update to Our Reader, Reviewer, and Author Communities-April 2020
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Update to Our Reader, Reviewer, and Author Communities - April 2020
From Russia, with Chemistry †
From Russia, with Chemistry †
Determination of the N–H Bond Dissociation Free Energy in a Pyridine(diimine)molybdenum Complex Prepared by Proton-Coupled Electron Transfer
Pyridine(diimine) Iron Diene Complexes Relevant to Catalytic [2+2]-Cycloaddition Reactions
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Update to Our Reader, Reviewer, and Author Communities - April 2020
Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters
Synthesis and Reactivity of Organometallic Intermediates Relevant to Cobalt-Catalyzed Hydroformylation
Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross Coupling
Dietmar Seyferth (1929–2020): A Foundational and Enduring Legacy at Organometallics
Using nature’s blueprint to expand catalysis with Earth-abundant metals
Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias
Actions at J. Org. Chem., Org. Lett. and Organometallics to Combat Discrimination and Bias
Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias
Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
C(sp2)–H Activation with Pyridine Dicarbene Iron Dialkyl Complexes: Hydrogen Isotope Exchange of Arenes Using Benzene-d6 as a Deuterium Source
Confronting Racism in Chemistry Journals
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant Intermediates
Confronting Racism in Chemistry Journals
Editorial Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Confronting Racism in Chemistry Journals
Update to Our Reader, Reviewer, and Author Communities.April 2020
Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
Update to Our Reader, Reviewer, and Author Communities-April 2020
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Update to Our Reader, Reviewer, and Author Communities-April 2020
Catalytic Hydrogenation of a Manganese(V) Nitride to Ammonia
Update to Our Reader, Reviewer, and Author Communities-April 2020
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Update to Our Reader, Reviewer, and Author Communities-April 2020
Pioneers and Influencers in Organometallic Chemistry: A Profile of Professor Jay Kochi
Investigations into the Mechanism of Inter- and Intramolecular Iron-Catalyzed [2+2] Cycloaddition of Alkenes
Cobalt-Catalyzed Asymmetric Hydrogenation of alpha,beta-Unsaturated Carboxylic Acids by Homolytic H-2 Cleavage
A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes
From Russia, With Chemistry
From Russia, With Chemistry
From Russia, With Chemistry
From Russia, With Chemistry
From Russia, With Chemistry
Ketone Synthesis from Benzyldiboronates and Esters: Leveraging alpha-Boryl Carbanions for Carbon-Carbon Bond Formation
Direct Observation of Transmetalation from a Neutral Boronate Ester to a Pyridine(diimine) Iron Alkoxide
2020 Vision: A Year for Pioneers and Influencers of Organometallic Chemistry
A fresh approach to synthesizing ammonia from air and water
Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance
Preface
Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters
[4 + 4]-cycloaddition of isoprene for the production of high-performance bio-based jet fuel
Remote, Diastereoselective Cobalt-Catalyzed Alkene Isomerization–Hydroboration: Access to Stereodefined 1,3-Difunctionalized Indanes
Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity
Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes
Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds
Cover Picture: Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds (Angew. Chem. Int. Ed. 27/2019)
Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications
Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes
Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer
Organometallics Global Enterprise
Pyridine(diimine) Chelate Hydrogenation in a Molybdenum Nitrido Ethylene Complex
N–H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer
Ni(I)-X Complexes Bearing a Bulky alpha-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals
Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand
Exploring C(sp3)–C(sp3) reductive elimination from an isolable iron metallacycle
Organometallics in 2019: It is Elementary
Exploring the Alcohol Stability of Bis(phosphine) Cobalt Dialkyl Precatalysts in Asymmetric Alkene Hydrogenation
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry †
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry †
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry †
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
Site-Selective Nickel-Catalyzed Hydrogen Isotope Exchange in N-Heterocycles and Its Application to the Tritiation of Pharmaceuticals
Cobalt Pincer Complexes in Catalytic C–H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes
Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a beta-Agostic Ethyl: Structure, Dynamics and Mechanism
Synthesis and Reactivity of Reduced alpha-Diimine Nickel Complexes Relevant to Acrylic Acid Synthesis
Iron-Mediated Coupling of Carbon Dioxide and Ethylene: Macrocyclic Metallalactones Enable Access to Various Carboxylates
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry
Dos and Don’ts: Thoughts on How To Respond to Reviewer Comments
Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes
Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity
Pyridine(diimine) Molybdenum-Catalyzed Hydrogenation of Arenes and Hindered Olefins: Insights into Precatalyst Activation and Deactivation Pathways
Cobalt-catalyzed asymmetric hydrogenation of enamides enabled by single-electron reduction
Ultrafast Photophysics of a Dinitrogen-Bridged Molybdenum Complex
Expanding the Boundaries of Organometallic Chemistry
Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts
Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer
Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer
Organometallics in 2018
Air-Stable alpha-Diimine Nickel Precatalysts for the Hydrogenation of Hindered, Unactivated Alkenes
Communicating Science
Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals
Insights into Activation of Cobalt Pre-Catalysts for C(sp(2))-H Functionalization
Synthesis and Reactivity of Pyridine(diimine) Molybdenum Olefin Complexes: Ethylene Dimerization and Alkene Dehydrogenation
Cobalt-Catalyzed C(sp2)-H borylation with an air-stable, readily prepared terpyridine cobalt(II) Bis(acetate) precatalyst
Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp3)–H Bonds
Mechanistic Studies of Cobalt-Catalyzed C(sp2)–H Borylation of Five-Membered Heteroarenes with Pinacolborane
Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand
Kohlenstoff-Kohlenstoff-Bindungsbildung in einem schwachen Ligandenfeld: Nutzung von Open-Shell-Übergangsmetallkatalysatoren der ersten Übergangsperiode
Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts
Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications
Introduction to the Virtual Issue Honoring Robert Bergman’s 2017 Wolf Prize in Chemistry
Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation
C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities
Organometallics in 2017: A Global Endeavor
Editorial: An award-winning tutorial
Cobalt-Catalyzed C(sp2)-H Borylation: Mechanistic Insights Inspire Catalyst Design
Alkene Hydrosilylation Using Tertiary Silanes with alpha-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts
Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes
Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen Complexes That Vary by Five Oxidation States
Cobalt-Catalyzed Enantioselective Hydrogenation of Minimally Functionalized Alkenes: Isotopic Labeling Provides Insight into the Origin of Stereoselectivity and Alkene Insertion Preferences
Nickel-Catalyzed Asymmetric Alkene Hydrogenation of alpha,beta-Unsaturated Esters: High-Throughput Experimentation-Enabled Reaction Discovery, Optimization, and Mechanistic Elucidation
Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling
Coordination-induced weakening of ammonia, water, and hydrazine X-H bonds in a molybdenum complex
Organometallics at 35: Personal Perspectives
Catalytic Proton Coupled Electron Transfer from Metal Hydrides to Titanocene Amides, Hydrazides and Imides: Determination of Thermodynamic Parameters Relevant to Nitrogen Fixation
An Editorial about Elemental Analysis
Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)-H Bonds
Iron-catalysed tritiation of pharmaceuticals
Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(II) diazenides and the influence of the trans ligand
Experimental absolute cross-sections for the reaction
Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals
A Meeting of Metals - A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes
Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes
Editorial: Organometallics Is a Changin' - The What, Why, and How
Cobalt-Catalyzed [2 pi+2 pi] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates
Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands
Alkene isomerization-hydroboration promoted by phosphine-ligated cobalt catalysts
Cobalt Catalyzed Z -Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity
Evaluation of Cobalt Complexes Bearing Tridentate Pincer Ligands for Catalytic C-H Borylation
Ammonia Synthesis by Hydrogenolysis of Titanium-Nitrogen Bonds Using Proton Coupled Electron Transfer
A career in catalysis: John E. bercaw
High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and alpha-Diimine Ligands
Synthesis and Electronic Structure of Iron Borate Betaine Complexes as a Route to Single-Component Iron Ethylene Oligomerization and Polymerization Catalysts
Editorial: Introducing Tutorials
Editorial: A new look, some new faces, and continuing the tradition of excellence
Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation
Carbon dioxide hydrosilylation promoted by cobalt pincer complexes
Photochemically induced reductive elimination as a route to a zirconocene complex with a strongly activated N2 ligand
N-H and N-C Bond Formation with an N-2-Derived Dihafnium mu-Nitrido Complex
Four-coordinate cobalt pincer complexes: Electronic structure studies and ligand modification by homolytic and heterolytic pathways
Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification
Oxidative addition and C-H activation chemistry with a PNP pincer-ligated cobalt complex
Cobalt-catalyzed C-H borylation
Synthesis and ligand modification chemistry of a molybdenum dinitrogen complex: Redox and chemical activity of a bis-(imino)pyridine ligand
Synthesis and carbonylation of oxotitanocyclobutanes derived from allene cycloaddition to a monomeric titanocene oxide
Synthesis and hydrogenation activity of iron dialkyl complexes with chiral bidentate phosphines
Electronic structure determination of pyridine N-heterocyclic carbene iron dinitrogen complexes and neutral ligand derivatives
Bis(imino)pyridine cobalt-catalyzed dehydrogenative silylation of alkenes: Scope, mechanism, and origins of selective allylsilane formation
Synthesis, electronic structure and reactivity of bis(imino)pyridine iron carbene complexes: Evidence for a carbene radical
N-N bond cleavage of 1,2-diarylhydrazines and N-H bond formation via H-atom transfer in vanadium complexes supported by a redox-active ligand
Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes
Synthesis of a base-free hafnium nitride from N2 cleavage: A versatile platform for dinitrogen functionalization
Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration
Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes
Reversible carbon-carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex
Synthesis and electronic structure of bis(imino)pyridine iron metallacyclic intermediates in iron-catalyzed cyclization reactions
Bis(imino)pyridine cobalt-catalyzed alkene isomerization-hydroboration: A strategy for remote hydrofunctionalization with terminal selectivity
Activation of dinitrogen-derived hafnium nitrides for nucleophilic N - C bond formation with a terminal isocyanate
Dinitrogen borylation with group 4 metallocene complexes
Oxidation and reduction of bis(imino)pyridine iron dinitrogen complexes: Evidence for formation of a chelate trianion.
Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts
Di- and tetrametallic hafnocene oxamidides prepared from CO-induced N2 bond cleavage and thermal rearrangement to hafnocene cyanide derivatives
High-activity iron catalysts for the hydrogenation of hindered, unfunctionalized alkenes
Synthesis, electronic structure, and alkene hydrosilylation activity of terpyridine and bis(imino)pyridine iron dialkyl complexes
Azo N=N bond cleavage with a redox-active vanadium compound involving metal-ligand cooperativity
Structure and Reactivity of a Hafnocene mu-Nitrido Prepared From Dinitrogen Cleavage
Side-on dinitrogen complexes of titanocenes with disubstituted cyclopentadienyl ligands: Synthesis, structure, and spectroscopic characterization
Electronic effects in 4-substituted bis(imino)pyridines and the corresponding reduced iron compounds
Bis(imino)pyridine iron dinitrogen compounds revisited: Differences in electronic structure between four- and five-coordinate derivatives.
Enantiopure C 1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation
Studies into the mechanism of CO-induced N 2 cleavage promoted by an Ansa-hafnocene complex and C-C bond formation from an observed intermediate
Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes
Oxidative addition of carbon-carbon bonds with a redox-active Bis(imino)pyridine iron complex
High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane
Synthesis and electronic structure of reduced bis(imino)pyridine manganese compounds
Synthesis, electronic structure, and ethylene polymerization activity of bis(imino)pyridine cobalt alkyl cations
Cyclisation of alpha,omega-dienes promoted by bis(indenyl)zirconium sandwich and ansa-titanocene dinitrogen complexes
Dinitrogen silylation and cleavage with a hafnocene complex
Iron-catalyzed intermolecular [2+2] cycloadditions
Synthesis, electronic structure, and catalytic activity of reduced bis(aldimino)pyridine iron compounds: Experimental evidence for ligand participation
Synthesis and electronic structure determination of N-alkyl-substituted bis(imino)pyridine iron imides exhibiting spin crossover behavior
Oxidation and reduction of bis(imino)pyridine iron dicarbonyl complexes
Preface: Forum on redox-active ligands
Carbon monoxide-induced dinitrogen cleavage with group 4 metallocenes: Reaction scope and coupling to N-H bond formation and CO deoxygenation
Reduced N -alkyl substituted bis(imino)pyridine cobalt complexes: Molecular and electronic structures for compounds varying by three oxidation states
Group 4 transition metal sandwich complexes: Still fresh after almost 60 years
Cyclopentanone insertion into n9-indenyl rings of zirconium sandwich complexes
Synthesis of aryl-substituted bis(imino) pyridine iron dinitrogen complexes
Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: Ligand versus metal reduction
Photolysis and thermolysis of bis(imino)pyridine cobalt azides: C-H activation from putative cobalt nitrido complexes
Functionalization of hafnium oxamidide complexes prepared from CO-induced N2 cleavage
Synthesis and electronic structure of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes: Evaluation of redox activity in single-component ethylene polymerization catalysts
Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex
1,4-addition of alkyl halides to a side-on bound bafnocene dinitrogen complex
Dinitrogen complexes of bis(cyclopentadienyl) titanium derivatives: Structural diversity arising from substituent manipulation
Enantiopure pyridine bis(oxazoline) "pybox" and bis(oxazoline) "box" iron dialkyl complexes: Comparison to bis(imino)pyridine compounds and application to catalytic hydrosilylation of ketones
Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent
Iron-catalyzed, hydrogen-mediated reductive cyclization of 1,6-enynes and diynes: Evidence for bis(imino)pyridine ligand participation
Bis(indenyl)hafnium chemistry: ligand-induced haptotropic rearrangement and fundamental reactivity studies at a reduced hafnium center
Addition of methyl triflate to a hafnocene dinitrogen complex: Stepwise N2 methylation and conversion to a hafnocene hydrazonato compound
Nitrogen fixation: One electron at a time
N-N bond cleavage in diazoalkanes by a Bis(imino)pyridine iron complex
Bis(imino)pyridine iron alkyls containing beta-hydrogens: Synthesis, evaluation of kinetic stability, and decomposition pathways involving chelate participation
Indenyl zirconium dinitrogen chemistry: N2 coordination to an isolated zirconium sandwich and synthesis of side-on, end-on dinitrogen compounds
Functional group tolerance and substrate scope in bis(imino)pyridine iron catalyzed alkene hydrogenation
Carboxylation of an ansa-zirconocene dinitrogen complex: Regiospecific hydrazine synthesis from N-2 and CO2
1,2-addition versus sigma-bond metathesis reactions in transient bis(cyclopentadienyl)zirconium imides: Evidence for a d(0) dihydrogen complex
Carbon-oxygen bond cleavage by bis(imino)pyridine iron compounds: Catalyst deactivation pathways and observation of acyl C-O bond cleavage in esters
Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation
N2 hydrogenation from activated end-on bis(indenyl) zirconium dinitrogen complexes
Synthesis of bis(imino)pyridine iron di- And monoalkyl complexes: Stability differences between FeCH2SiMe3 and FeCH 2CMe3 derivatives
Neutral-ligand complexes of bis(imino)pyridine iron: Synthesis, structure, and spectroscopy
Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes
N-H group transfer and oxidative addition chemistry promoted by isolable bis(cyclopentadienyl)titanium sandwich complexes
Nitrogen-carbon bond formation from N2 and CO2 promoted by a hafnocene dinitrogen complex yields a substituted hydrazine
C-O and C-S bond cleavage in chelating diethers and thioethers promoted by eta(9),eta(5)-bis(indenyl)zirconium sandwich complexes: A combined experimental and computational study
Iron diazoalkane chemistry: N-N bond hydrogenation and intramolecular C-H activation
Bis(cyclopentadienyl) titanium dinitrogen chemistry: Synthesis and characterization of a side-on bound haptomer
Dihydrogen and silane addition to base-free, monomeric bis(cyclopentadienyl)titanium oxides
Diazene dehydrogenation follows H2 addition to coordinated dinitrogen in an ansa-zirconocene complex
Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium
Bis(diisopropylphosphino)pyridine iron dicarbonyl, dihydride, and silyl hydride complexes
Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation
N-C bond formation promoted by a hafnocene dinitrogen complex: Comparison of zirconium and hafnium congeners
Synthesis of bis(indenyl)zirconium dihydrides and subsequent rearrangement to eta(5),eta(3)-4,5-dihydroindenediyl ligands: Evidence for intermediates during the hydrogenation to tetrahydroindenyl derivatives
Mono(dinitrogen) and carbon monoxide adducts of bis(cyclopentadienyl) titanium sandwiches
Synthesis and hydrogenation of bis(imino)pyridine iron imides
The "indenyl effect" in zirconocene dihydride chemistry
Carbon-hydrogen bond activation with a cyclometalated zirconocene hydride: Mechanistic differences between arene and alkane reductive elimination
N 2 hydrogenation promoted by a side-on bound hafnocene dinitrogen complex
Carbon-oxygen bond cleavage with eta(9),eta(5)-bis(indenyl)zirconium sandwich complexes
An FeVI nitride: There is plenty of room at the top!
Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: A combined structural, spectroscopic, and computational study
Iron-catalyzed [2 pi+2 pi] cycloaddition of alpha,omega-dienes: The importance of redox-active supporting ligands
Bis(imino)pyridine ligand deprotonation promoted by a transient iron amide
C-H bond activation reactions with ligand adducts of a beta-diiminate iridium dihydride
Ligand-induced haptotropic rearrangements in bis(indenyl)zirconium sandwich complexes
Square planar bis(imino)pyridine iron halide and alkyl complexes
Bis(imino)pyridine iron(II) alkyl cations for olefin polymerization
Dinitrogen functionalization with terminal alkynes, amines, and hydrazines promoted by [(eta(5)-C5Me4H)(2)Zr](2)(mu(2),eta(2) eta(2)-N-2): Observation of side-on and end-on diazenido complexes in the reduction of N-2 to hydrazine
Experimental evidence for gamma-agostic assistance in beta-methyl elimination, the microscopic reverse of alpha-agostic assistance in the chain propagation step of olefin polymerization
Square planar vs tetrahedral geometry in four coordinate iron(II) complexes
The importance of cyclopentadienyl substituent effects in group 4 metallocene dinitrogen chemistry
Ancillary ligand effects on C-H bond activation reactions promoted by beta-diiminate iridium complexes
Low-valent alpha-diimine iron complexes for catalytic olefin hydrogenation
Cyclopentadienyl and olefin substituent effects on insertion and beta-hydrogen elimination with group 4 metallocenes. Kinetics, mechanism, and thermodynamics for zirconocene and hafnocene alkyl hydride derivatives
Kinetics and mechanism of N2 hydrogenation in bis(cyclopentadienyl) zirconium complexes and dinitrogen functionalization by 1,2-addition of a saturated C-H bond
Synthesis of a base-free titanium imido and a transient alkylidene from a titanocene dinitrogen complex. Studies on Ti=NR hydrogenation, nitrene group transfer, and comparison of 1,2-addition rates
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
Zirconium sandwich complexes with eta(9) indenyl ligands: Well-defined precursors for zirconocene-mediated coupling reactions
Dinitrogen activation by titanium sandwich complexes
On the origin of dinitrogen hydrogenation promoted by [(eta(5)-C5Me4H)(2)Zr](2)(mu(2),eta(2),eta(2)-N2)
Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation
Synthesis and characterization of zirconium and iron complexes containing substituted indenyl ligands: Evaluation of steric and electronic parameters
Synthesis, Reactivity, and Solid State Structures of Four-Coordinate Iron(II) and Manganese(II) Alkyl Complexes
Synthesis of a beta-diiminate iridium tetrahydride for arene C–H bond activation
Synthesis of a zirconium sandwich complex and crystallographic characterization of its adduct with tetrahydrofuran
Alkyl substituent effects on reductive elimination reactions in zirconocene alkyl hydride complexes. Manipulation of the alkyl steric environment allows the synthesis of a zirconocene dinitrogen complex
Cyclopentadienyl substituent effects on reductive elimination reactions in group 4 metallocenes: Kinetics, mechanism, and application to dinitrogen activation
Selective, catalytic carbon-carbon bond activation and functionalization promoted by late transition metal catalysts
Preparation of ansa-niobocene and ansa-tantalocene olefin hydride complexes as transition state analogues in metallocene-catalyzed olefin polymerization
Functionalization of elemental phosphorus with [Zr(eta5- C5Me5) (eta5-C5H4tBu)H2]2
A convenient method for the synthesis of zirconocene hydrido chloride, isobutyl hydride, and dihydride complexes using tert-butyl lithium
Synthesis of singly and doubly bridged ansa-zirconocene hydrides. Formation of an unusual mixed valence trimeric hydride by reaction of H-2 with {(Me2Si)(2)(eta(5)-C5H3)(2)}Zr(CH3)(2) and generation of a dinitrogen complex by reaction of N-2 with a zirconocene dihydride
Mechanistic aspects of chain propagation and transfer for metallocene-catalyzed olefin polymerization
Preparation and characterization of monomeric and dimeric group IV metallocene dihydrides having alkyl- substituted cyclopentadienyl ligands
Alkyl rearrangement processes in organozirconium complexes. Observation of internal alkyl complexes during hydrozirconation
Libros, capítulos, tesis Todos / Ninguno
Determining and understanding N-H bond strengths in synthetic nitrogen fixation cycles
Electronic Structures of Reduced Manganese, Iron, and Cobalt Complexes Bearing Redox-Active Bis(imino)pyridine Pincer Ligands
Bis(n5-Pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium
Modern Alchemy: Replacing Precious Metals with Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions
Complexes of zirconium and hafnium in oxidation states 0 to II
Complexes of titanium in oxidation states 0 to II
Conferencias Todos / Ninguno
Dinitrogen cleavage with carbon monoxide and silanes
Informes y otros Todos / Ninguno
Erratum: Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance (Chem (2019) 5(2) (402–416), (S2451929418305205), (10.1016/j.chempr.2018.11.003))
Erratum: Cobalt-catalyzed C(sp2)-H borylation with an air-stable, readily prepared terpyridine cobalt(II) bis(acetate) precatalyst (Organometallics (2017) 36:1 (142-150) DOI: 10.1021/acs.organomet.6b00630)
Green Chemistry: A Framework for a Sustainable Future
Confronting Racism in Chemistry Journals
Iron Catalyzed Synthesis and Chemical Recycling of Telechelic, 1,3-Enchained Oligocyclobutanes
N-N bond cleavage in diazoalkanes by a bis(imino)pyridine iron complex
Radical ligands confer nobility on base-metal catalysts
Métricas del autor Todos / Ninguno
Indice H