Introducing the Author’s Corner |
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Bimolecular Reductive Elimination of Ethane from Pyridine(diimine) Iron Methyl Complexes: Mechanism, Electronic Structure, and Entry into [2+2] Cycloaddition Catalysis |
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Kinetic and thermodynamic control of C(sp 2 )–H activation enables site-selective borylation |
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A butadiene-derived semicrystalline polyolefin with two-tiered chemical recyclability |
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Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists** |
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Iridium-Catalyzed Hydrogenation of a Phenoxy Radical to the Phenol: Overcoming Catalyst Deactivation with Visible Light Irradiation |
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Quinoline Pyridine(Imine) Iron Complexes as Catalysts for the 1,4-Hydrovinylation of 1,3-Dienes |
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Arene Insertion with Pincer-Supported Molybdenum-Hydrides: Determination of Site Selectivity, Relative Rates, and Arene Complex Formation |
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Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling |
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CS-Symmetric Pyridine(diimine) Iron Methyl Complexes for Catalytic [2+2] Cycloaddition and Hydrovinylation: Metallacycle Geometry Determines Selectivity |
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C(sp3)–C(sp2) Reductive Elimination versus β-Hydride Elimination from Cobalt(III) Intermediates in Catalytic C–H Functionalization |
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Asymmetric Hydrogenation of Indazole-Containing Enamides Relevant to the Synthesis of Zavegepant Using Neutral and Cationic Cobalt Precatalysts |
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Exploring the Effect of Pincer Rigidity on Oxidative Addition Reactions with Cobalt(I) Complexes |
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Collaboration as a Key to Advance Capabilities for Earth-Abundant Metal Catalysis |
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Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures |
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Iron-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Using an Alkoxide Base |
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Scoping Out 2023 |
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Identification of Cyclohexadienyl Hydrides as Intermediates in Molybdenum‐Catalyzed Arene Hydrogenation |
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Catalytic N–H Bond Formation Promoted by a Ruthenium Hydride Complex Bearing a Redox-Active Pyrimidine-Imine Ligand |
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Alcohol Synthesis by Cobalt-Catalyzed Visible-Light-Driven Reductive Hydroformylation |
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C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles |
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Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts |
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Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects |
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Nickel-Catalyzed Dimerization of Di- and Trisubstituted Olefins |
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C(sp2)–H Activation with Bis(silylene)pyridine Cobalt(III) Complexes: Catalytic Hydrogen Isotope Exchange of Sterically Hindered C–H Bonds |
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Pioneers and Influencers in Organometallic Chemistry: A Profile of Dr. Barbara Burger |
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Molybdenum-Catalyzed Asymmetric Hydrogenation of Fused Arenes and Heteroarenes |
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Development of Cobalt Catalysts for the meta-Selective C(sp2)–H Borylation of Fluorinated Arenes |
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Cationic Bis(phosphine) Cobalt(I) Arene Complexes as Precatalysts for the Asymmetric Synthesis of Sitagliptin |
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Ammonia synthesis by photocatalytic hydrogenation of a N2-derived molybdenum nitride |
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Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization |
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(PNP)Cobalt-Catalyzed Olefination of Diazoalkanes |
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Making 2022 Picture Perfect |
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Visible-Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates, and Catalyst Improvements |
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Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands |
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Green Chemistry: A Framework for a Sustainable Future |
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40 Years of Organometallics |
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Well-Defined Cationic Cobalt(I) Precatalyst for Olefin-Alkyne [2 + 2] Cycloaddition and Olefin-Diene Hydrovinylation Reactions: Experimental Evidence for Metallacycle Intermediates |
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Green Chemistry: A Framework for a Sustainable Future |
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Synthesis, Electronic Structure, and Reactivity of a Planar Four-Coordinate, Cobalt–Imido Complex |
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Effect of Pincer Methylation on the Selectivity and Activity in (PNP)Cobalt-Catalyzed C(sp2)-H Borylation |
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Catalyst Design Principles Enabling Intermolecular Alkene-Diene [2+2] Cycloaddition and Depolymerization Reactions |
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Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen |
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Ligand substitution and electronic structure studies of bis(Phosphine)cobalt cyclooctadiene precatalysts for alkene hydrogenation |
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Green Chemistry: A Framework for a Sustainable Future |
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Green chemistry: A framework for a sustainable future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green chemistry: A framework for a sustainable future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Green Chemistry: A Framework for a Sustainable Future |
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Oxidative Addition of Aryl and Alkyl Halides to a Reduced Iron Pincer Complex |
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Synthesis and Asymmetric Alkene Hydrogenation Activity of C2-Symmetric Enantioenriched Pyridine Dicarbene Iron Dialkyl Complexes |
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A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes |
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Pioneers and Influencers: A Profile of Dr. Kenrick Lewis |
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Iron-catalysed synthesis and chemical recycling of telechelic 1,3-enchained oligocyclobutanes |
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Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenation: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways |
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Iron-Catalyzed Vinylsilane Dimerization and Cross-Cycloadditions with 1,3-Dienes: Probing the Origins of Chemo- and Regioselectivity |
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Looking Forward to 2021: The Fabulous Forties! |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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From Russia, with Chemistry † |
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From Russia, with Chemistry † |
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Determination of the N–H Bond Dissociation Free Energy in a Pyridine(diimine)molybdenum Complex Prepared by Proton-Coupled Electron Transfer |
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Pyridine(diimine) Iron Diene Complexes Relevant to Catalytic [2+2]-Cycloaddition Reactions |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Update to Our Reader, Reviewer, and Author Communities - April 2020 |
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Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters |
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Synthesis and Reactivity of Organometallic Intermediates Relevant to Cobalt-Catalyzed Hydroformylation |
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Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross Coupling |
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Dietmar Seyferth (1929–2020): A Foundational and Enduring Legacy at Organometallics |
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Using nature’s blueprint to expand catalysis with Earth-abundant metals |
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Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias |
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Actions at J. Org. Chem., Org. Lett. and Organometallics to Combat Discrimination and Bias |
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Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias |
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Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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C(sp2)–H Activation with Pyridine Dicarbene Iron Dialkyl Complexes: Hydrogen Isotope Exchange of Arenes Using Benzene-d6 as a Deuterium Source |
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Confronting Racism in Chemistry Journals |
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Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant Intermediates |
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Confronting Racism in Chemistry Journals |
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Editorial Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Confronting Racism in Chemistry Journals |
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Update to Our Reader, Reviewer, and Author Communities.April 2020 |
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Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Catalytic Hydrogenation of a Manganese(V) Nitride to Ammonia |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Update to Our Reader, Reviewer, and Author Communities-April 2020 |
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Pioneers and Influencers in Organometallic Chemistry: A Profile of Professor Jay Kochi |
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Investigations into the Mechanism of Inter- and Intramolecular Iron-Catalyzed [2+2] Cycloaddition of Alkenes |
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Cobalt-Catalyzed Asymmetric Hydrogenation of alpha,beta-Unsaturated Carboxylic Acids by Homolytic H-2 Cleavage |
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A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes |
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From Russia, With Chemistry |
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From Russia, With Chemistry |
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From Russia, With Chemistry |
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From Russia, With Chemistry |
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From Russia, With Chemistry |
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Ketone Synthesis from Benzyldiboronates and Esters: Leveraging alpha-Boryl Carbanions for Carbon-Carbon Bond Formation |
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Direct Observation of Transmetalation from a Neutral Boronate Ester to a Pyridine(diimine) Iron Alkoxide |
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2020 Vision: A Year for Pioneers and Influencers of Organometallic Chemistry |
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A fresh approach to synthesizing ammonia from air and water |
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Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance |
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Preface |
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Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters |
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[4 + 4]-cycloaddition of isoprene for the production of high-performance bio-based jet fuel |
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Remote, Diastereoselective Cobalt-Catalyzed Alkene Isomerization–Hydroboration: Access to Stereodefined 1,3-Difunctionalized Indanes |
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Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity |
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Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes |
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Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds |
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Cover Picture: Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds (Angew. Chem. Int. Ed. 27/2019) |
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Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications |
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Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes |
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Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer |
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Organometallics Global Enterprise |
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Pyridine(diimine) Chelate Hydrogenation in a Molybdenum Nitrido Ethylene Complex |
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N–H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer |
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Ni(I)-X Complexes Bearing a Bulky alpha-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals |
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Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand |
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Exploring C(sp3)–C(sp3) reductive elimination from an isolable iron metallacycle |
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Organometallics in 2019: It is Elementary |
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Exploring the Alcohol Stability of Bis(phosphine) Cobalt Dialkyl Precatalysts in Asymmetric Alkene Hydrogenation |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry † |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry † |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry † |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration |
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Site-Selective Nickel-Catalyzed Hydrogen Isotope Exchange in N-Heterocycles and Its Application to the Tritiation of Pharmaceuticals |
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Cobalt Pincer Complexes in Catalytic C–H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes |
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Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a beta-Agostic Ethyl: Structure, Dynamics and Mechanism |
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Synthesis and Reactivity of Reduced alpha-Diimine Nickel Complexes Relevant to Acrylic Acid Synthesis |
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Iron-Mediated Coupling of Carbon Dioxide and Ethylene: Macrocyclic Metallalactones Enable Access to Various Carboxylates |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry |
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Dos and Don’ts: Thoughts on How To Respond to Reviewer Comments |
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Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes |
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Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity |
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Pyridine(diimine) Molybdenum-Catalyzed Hydrogenation of Arenes and Hindered Olefins: Insights into Precatalyst Activation and Deactivation Pathways |
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Cobalt-catalyzed asymmetric hydrogenation of enamides enabled by single-electron reduction |
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Ultrafast Photophysics of a Dinitrogen-Bridged Molybdenum Complex |
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Expanding the Boundaries of Organometallic Chemistry |
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Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts |
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Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer |
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Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer |
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Organometallics in 2018 |
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Air-Stable alpha-Diimine Nickel Precatalysts for the Hydrogenation of Hindered, Unactivated Alkenes |
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Communicating Science |
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Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals |
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Insights into Activation of Cobalt Pre-Catalysts for C(sp(2))-H Functionalization |
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Synthesis and Reactivity of Pyridine(diimine) Molybdenum Olefin Complexes: Ethylene Dimerization and Alkene Dehydrogenation |
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Cobalt-Catalyzed C(sp2)-H borylation with an air-stable, readily prepared terpyridine cobalt(II) Bis(acetate) precatalyst |
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Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp3)–H Bonds |
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Mechanistic Studies of Cobalt-Catalyzed C(sp2)–H Borylation of Five-Membered Heteroarenes with Pinacolborane |
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Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand |
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Kohlenstoff-Kohlenstoff-Bindungsbildung in einem schwachen Ligandenfeld: Nutzung von Open-Shell-Übergangsmetallkatalysatoren der ersten Übergangsperiode |
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Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts |
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Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications |
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Introduction to the Virtual Issue Honoring Robert Bergman’s 2017 Wolf Prize in Chemistry |
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Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation |
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C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities |
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Organometallics in 2017: A Global Endeavor |
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Editorial: An award-winning tutorial |
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Cobalt-Catalyzed C(sp2)-H Borylation: Mechanistic Insights Inspire Catalyst Design |
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Alkene Hydrosilylation Using Tertiary Silanes with alpha-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts |
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Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes |
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Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen Complexes That Vary by Five Oxidation States |
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Cobalt-Catalyzed Enantioselective Hydrogenation of Minimally Functionalized Alkenes: Isotopic Labeling Provides Insight into the Origin of Stereoselectivity and Alkene Insertion Preferences |
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Nickel-Catalyzed Asymmetric Alkene Hydrogenation of alpha,beta-Unsaturated Esters: High-Throughput Experimentation-Enabled Reaction Discovery, Optimization, and Mechanistic Elucidation |
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Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling |
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Coordination-induced weakening of ammonia, water, and hydrazine X-H bonds in a molybdenum complex |
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Organometallics at 35: Personal Perspectives |
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Catalytic Proton Coupled Electron Transfer from Metal Hydrides to Titanocene Amides, Hydrazides and Imides: Determination of Thermodynamic Parameters Relevant to Nitrogen Fixation |
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An Editorial about Elemental Analysis |
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Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)-H Bonds |
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Iron-catalysed tritiation of pharmaceuticals |
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Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(II) diazenides and the influence of the trans ligand |
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Experimental absolute cross-sections for the reaction |
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Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals |
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A Meeting of Metals - A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes |
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Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes |
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Editorial: Organometallics Is a Changin' - The What, Why, and How |
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Cobalt-Catalyzed [2 pi+2 pi] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates |
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Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands |
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Alkene isomerization-hydroboration promoted by phosphine-ligated cobalt catalysts |
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Cobalt Catalyzed Z -Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity |
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Evaluation of Cobalt Complexes Bearing Tridentate Pincer Ligands for Catalytic C-H Borylation |
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Ammonia Synthesis by Hydrogenolysis of Titanium-Nitrogen Bonds Using Proton Coupled Electron Transfer |
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A career in catalysis: John E. bercaw |
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High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and alpha-Diimine Ligands |
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Synthesis and Electronic Structure of Iron Borate Betaine Complexes as a Route to Single-Component Iron Ethylene Oligomerization and Polymerization Catalysts |
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Editorial: Introducing Tutorials |
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Editorial: A new look, some new faces, and continuing the tradition of excellence |
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Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation |
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Carbon dioxide hydrosilylation promoted by cobalt pincer complexes |
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Photochemically induced reductive elimination as a route to a zirconocene complex with a strongly activated N2 ligand |
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N-H and N-C Bond Formation with an N-2-Derived Dihafnium mu-Nitrido Complex |
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Four-coordinate cobalt pincer complexes: Electronic structure studies and ligand modification by homolytic and heterolytic pathways |
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Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification |
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Oxidative addition and C-H activation chemistry with a PNP pincer-ligated cobalt complex |
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Cobalt-catalyzed C-H borylation |
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Synthesis and ligand modification chemistry of a molybdenum dinitrogen complex: Redox and chemical activity of a bis-(imino)pyridine ligand |
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Synthesis and carbonylation of oxotitanocyclobutanes derived from allene cycloaddition to a monomeric titanocene oxide |
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Synthesis and hydrogenation activity of iron dialkyl complexes with chiral bidentate phosphines |
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Electronic structure determination of pyridine N-heterocyclic carbene iron dinitrogen complexes and neutral ligand derivatives |
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Bis(imino)pyridine cobalt-catalyzed dehydrogenative silylation of alkenes: Scope, mechanism, and origins of selective allylsilane formation |
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Synthesis, electronic structure and reactivity of bis(imino)pyridine iron carbene complexes: Evidence for a carbene radical |
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N-N bond cleavage of 1,2-diarylhydrazines and N-H bond formation via H-atom transfer in vanadium complexes supported by a redox-active ligand |
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Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes |
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Synthesis of a base-free hafnium nitride from N2 cleavage: A versatile platform for dinitrogen functionalization |
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Highly selective bis(imino)pyridine iron-catalyzed alkene hydroboration |
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Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes |
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Reversible carbon-carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex |
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Synthesis and electronic structure of bis(imino)pyridine iron metallacyclic intermediates in iron-catalyzed cyclization reactions |
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Bis(imino)pyridine cobalt-catalyzed alkene isomerization-hydroboration: A strategy for remote hydrofunctionalization with terminal selectivity |
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Activation of dinitrogen-derived hafnium nitrides for nucleophilic N - C bond formation with a terminal isocyanate |
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Dinitrogen borylation with group 4 metallocene complexes |
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Oxidation and reduction of bis(imino)pyridine iron dinitrogen complexes: Evidence for formation of a chelate trianion. |
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Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts |
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Di- and tetrametallic hafnocene oxamidides prepared from CO-induced N2 bond cleavage and thermal rearrangement to hafnocene cyanide derivatives |
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High-activity iron catalysts for the hydrogenation of hindered, unfunctionalized alkenes |
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Synthesis, electronic structure, and alkene hydrosilylation activity of terpyridine and bis(imino)pyridine iron dialkyl complexes |
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Azo N=N bond cleavage with a redox-active vanadium compound involving metal-ligand cooperativity |
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Structure and Reactivity of a Hafnocene mu-Nitrido Prepared From Dinitrogen Cleavage |
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Side-on dinitrogen complexes of titanocenes with disubstituted cyclopentadienyl ligands: Synthesis, structure, and spectroscopic characterization |
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Electronic effects in 4-substituted bis(imino)pyridines and the corresponding reduced iron compounds |
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Bis(imino)pyridine iron dinitrogen compounds revisited: Differences in electronic structure between four- and five-coordinate derivatives. |
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Enantiopure C 1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation |
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Studies into the mechanism of CO-induced N 2 cleavage promoted by an Ansa-hafnocene complex and C-C bond formation from an observed intermediate |
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Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes |
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Oxidative addition of carbon-carbon bonds with a redox-active Bis(imino)pyridine iron complex |
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High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane |
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Synthesis and electronic structure of reduced bis(imino)pyridine manganese compounds |
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Synthesis, electronic structure, and ethylene polymerization activity of bis(imino)pyridine cobalt alkyl cations |
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Cyclisation of alpha,omega-dienes promoted by bis(indenyl)zirconium sandwich and ansa-titanocene dinitrogen complexes |
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Dinitrogen silylation and cleavage with a hafnocene complex |
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Iron-catalyzed intermolecular [2+2] cycloadditions |
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Synthesis, electronic structure, and catalytic activity of reduced bis(aldimino)pyridine iron compounds: Experimental evidence for ligand participation |
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Synthesis and electronic structure determination of N-alkyl-substituted bis(imino)pyridine iron imides exhibiting spin crossover behavior |
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Oxidation and reduction of bis(imino)pyridine iron dicarbonyl complexes |
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Preface: Forum on redox-active ligands |
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Carbon monoxide-induced dinitrogen cleavage with group 4 metallocenes: Reaction scope and coupling to N-H bond formation and CO deoxygenation |
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Reduced N -alkyl substituted bis(imino)pyridine cobalt complexes: Molecular and electronic structures for compounds varying by three oxidation states |
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Group 4 transition metal sandwich complexes: Still fresh after almost 60 years |
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Cyclopentanone insertion into n9-indenyl rings of zirconium sandwich complexes |
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Synthesis of aryl-substituted bis(imino) pyridine iron dinitrogen complexes |
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Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: Ligand versus metal reduction |
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Photolysis and thermolysis of bis(imino)pyridine cobalt azides: C-H activation from putative cobalt nitrido complexes |
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Functionalization of hafnium oxamidide complexes prepared from CO-induced N2 cleavage |
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Synthesis and electronic structure of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes: Evaluation of redox activity in single-component ethylene polymerization catalysts |
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Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex |
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1,4-addition of alkyl halides to a side-on bound bafnocene dinitrogen complex |
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Dinitrogen complexes of bis(cyclopentadienyl) titanium derivatives: Structural diversity arising from substituent manipulation |
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Enantiopure pyridine bis(oxazoline) "pybox" and bis(oxazoline) "box" iron dialkyl complexes: Comparison to bis(imino)pyridine compounds and application to catalytic hydrosilylation of ketones |
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Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent |
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Iron-catalyzed, hydrogen-mediated reductive cyclization of 1,6-enynes and diynes: Evidence for bis(imino)pyridine ligand participation |
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Bis(indenyl)hafnium chemistry: ligand-induced haptotropic rearrangement and fundamental reactivity studies at a reduced hafnium center |
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Addition of methyl triflate to a hafnocene dinitrogen complex: Stepwise N2 methylation and conversion to a hafnocene hydrazonato compound |
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Nitrogen fixation: One electron at a time |
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N-N bond cleavage in diazoalkanes by a Bis(imino)pyridine iron complex |
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Bis(imino)pyridine iron alkyls containing beta-hydrogens: Synthesis, evaluation of kinetic stability, and decomposition pathways involving chelate participation |
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Indenyl zirconium dinitrogen chemistry: N2 coordination to an isolated zirconium sandwich and synthesis of side-on, end-on dinitrogen compounds |
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Functional group tolerance and substrate scope in bis(imino)pyridine iron catalyzed alkene hydrogenation |
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Carboxylation of an ansa-zirconocene dinitrogen complex: Regiospecific hydrazine synthesis from N-2 and CO2 |
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1,2-addition versus sigma-bond metathesis reactions in transient bis(cyclopentadienyl)zirconium imides: Evidence for a d(0) dihydrogen complex |
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Carbon-oxygen bond cleavage by bis(imino)pyridine iron compounds: Catalyst deactivation pathways and observation of acyl C-O bond cleavage in esters |
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Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation |
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N2 hydrogenation from activated end-on bis(indenyl) zirconium dinitrogen complexes |
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Synthesis of bis(imino)pyridine iron di- And monoalkyl complexes: Stability differences between FeCH2SiMe3 and FeCH 2CMe3 derivatives |
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Neutral-ligand complexes of bis(imino)pyridine iron: Synthesis, structure, and spectroscopy |
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Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes |
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N-H group transfer and oxidative addition chemistry promoted by isolable bis(cyclopentadienyl)titanium sandwich complexes |
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Nitrogen-carbon bond formation from N2 and CO2 promoted by a hafnocene dinitrogen complex yields a substituted hydrazine |
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C-O and C-S bond cleavage in chelating diethers and thioethers promoted by eta(9),eta(5)-bis(indenyl)zirconium sandwich complexes: A combined experimental and computational study |
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Iron diazoalkane chemistry: N-N bond hydrogenation and intramolecular C-H activation |
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Bis(cyclopentadienyl) titanium dinitrogen chemistry: Synthesis and characterization of a side-on bound haptomer |
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Dihydrogen and silane addition to base-free, monomeric bis(cyclopentadienyl)titanium oxides |
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Diazene dehydrogenation follows H2 addition to coordinated dinitrogen in an ansa-zirconocene complex |
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Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium |
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Bis(diisopropylphosphino)pyridine iron dicarbonyl, dihydride, and silyl hydride complexes |
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Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation |
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N-C bond formation promoted by a hafnocene dinitrogen complex: Comparison of zirconium and hafnium congeners |
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Synthesis of bis(indenyl)zirconium dihydrides and subsequent rearrangement to eta(5),eta(3)-4,5-dihydroindenediyl ligands: Evidence for intermediates during the hydrogenation to tetrahydroindenyl derivatives |
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Mono(dinitrogen) and carbon monoxide adducts of bis(cyclopentadienyl) titanium sandwiches |
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Synthesis and hydrogenation of bis(imino)pyridine iron imides |
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The "indenyl effect" in zirconocene dihydride chemistry |
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Carbon-hydrogen bond activation with a cyclometalated zirconocene hydride: Mechanistic differences between arene and alkane reductive elimination |
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N 2 hydrogenation promoted by a side-on bound hafnocene dinitrogen complex |
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Carbon-oxygen bond cleavage with eta(9),eta(5)-bis(indenyl)zirconium sandwich complexes |
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An FeVI nitride: There is plenty of room at the top! |
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Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: A combined structural, spectroscopic, and computational study |
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Iron-catalyzed [2 pi+2 pi] cycloaddition of alpha,omega-dienes: The importance of redox-active supporting ligands |
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Bis(imino)pyridine ligand deprotonation promoted by a transient iron amide |
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C-H bond activation reactions with ligand adducts of a beta-diiminate iridium dihydride |
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Ligand-induced haptotropic rearrangements in bis(indenyl)zirconium sandwich complexes |
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Square planar bis(imino)pyridine iron halide and alkyl complexes |
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Bis(imino)pyridine iron(II) alkyl cations for olefin polymerization |
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Dinitrogen functionalization with terminal alkynes, amines, and hydrazines promoted by [(eta(5)-C5Me4H)(2)Zr](2)(mu(2),eta(2) eta(2)-N-2): Observation of side-on and end-on diazenido complexes in the reduction of N-2 to hydrazine |
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Experimental evidence for gamma-agostic assistance in beta-methyl elimination, the microscopic reverse of alpha-agostic assistance in the chain propagation step of olefin polymerization |
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Square planar vs tetrahedral geometry in four coordinate iron(II) complexes |
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The importance of cyclopentadienyl substituent effects in group 4 metallocene dinitrogen chemistry |
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Ancillary ligand effects on C-H bond activation reactions promoted by beta-diiminate iridium complexes |
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Low-valent alpha-diimine iron complexes for catalytic olefin hydrogenation |
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Cyclopentadienyl and olefin substituent effects on insertion and beta-hydrogen elimination with group 4 metallocenes. Kinetics, mechanism, and thermodynamics for zirconocene and hafnocene alkyl hydride derivatives |
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Kinetics and mechanism of N2 hydrogenation in bis(cyclopentadienyl) zirconium complexes and dinitrogen functionalization by 1,2-addition of a saturated C-H bond |
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Synthesis of a base-free titanium imido and a transient alkylidene from a titanocene dinitrogen complex. Studies on Ti=NR hydrogenation, nitrene group transfer, and comparison of 1,2-addition rates |
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Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex |
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Zirconium sandwich complexes with eta(9) indenyl ligands: Well-defined precursors for zirconocene-mediated coupling reactions |
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Dinitrogen activation by titanium sandwich complexes |
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On the origin of dinitrogen hydrogenation promoted by [(eta(5)-C5Me4H)(2)Zr](2)(mu(2),eta(2),eta(2)-N2) |
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Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation |
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Synthesis and characterization of zirconium and iron complexes containing substituted indenyl ligands: Evaluation of steric and electronic parameters |
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Synthesis, Reactivity, and Solid State Structures of Four-Coordinate Iron(II) and Manganese(II) Alkyl Complexes |
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Synthesis of a beta-diiminate iridium tetrahydride for arene C–H bond activation |
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Synthesis of a zirconium sandwich complex and crystallographic characterization of its adduct with tetrahydrofuran |
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Alkyl substituent effects on reductive elimination reactions in zirconocene alkyl hydride complexes. Manipulation of the alkyl steric environment allows the synthesis of a zirconocene dinitrogen complex |
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Cyclopentadienyl substituent effects on reductive elimination reactions in group 4 metallocenes: Kinetics, mechanism, and application to dinitrogen activation |
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Selective, catalytic carbon-carbon bond activation and functionalization promoted by late transition metal catalysts |
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Preparation of ansa-niobocene and ansa-tantalocene olefin hydride complexes as transition state analogues in metallocene-catalyzed olefin polymerization |
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Functionalization of elemental phosphorus with [Zr(eta5- C5Me5) (eta5-C5H4tBu)H2]2 |
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A convenient method for the synthesis of zirconocene hydrido chloride, isobutyl hydride, and dihydride complexes using tert-butyl lithium |
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Synthesis of singly and doubly bridged ansa-zirconocene hydrides. Formation of an unusual mixed valence trimeric hydride by reaction of H-2 with {(Me2Si)(2)(eta(5)-C5H3)(2)}Zr(CH3)(2) and generation of a dinitrogen complex by reaction of N-2 with a zirconocene dihydride |
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Mechanistic aspects of chain propagation and transfer for metallocene-catalyzed olefin polymerization |
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Preparation and characterization of monomeric and dimeric group IV metallocene dihydrides having alkyl- substituted cyclopentadienyl ligands |
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Alkyl rearrangement processes in organozirconium complexes. Observation of internal alkyl complexes during hydrozirconation |
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