| High-pressure and high-temperature synthesis of crystalline Sb<inf>3</inf>N<inf>5</inf> |
|
| Anisotropic thermo-mechanical response of layered hexagonal boron nitride and black phosphorus: application as a simultaneous pressure and temperature sensor |
|
| Stability, Chemical Bonding, and Electron Lone Pair Localization in AsN at High Pressure by Density Functional Theory Calculations |
|
| Solid acid catalysts for low-temperature regeneration of non-aqueous sorbents: An innovative technique for energy-efficient CO<sub>2</sub> capture processes |
|
| Electrochemistry: from Alessandro Volta’s genius to the future |
|
| Propagation of visible light in nanostructured niobium stripes embedded in a dielectric polymer |
|
| High-Pressure and High-Temperature Chemistry of Phosphorus and Nitrogen: Synthesis and Characterization of α- and γ-P3N5 |
|
| Evidence of Josephson Coupling in a Few-Layer Black Phosphorus Planar Josephson Junction |
|
| Easy and fast in situ functionalization of exfoliated 2D black phosphorus with gold nanoparticles |
|
| Large-Area Oxidized Phosphorene Nanoflakes Obtained by Electrospray for Energy-Harvesting Applications |
|
| Interfacial chemistry and electroactivity of black phosphorus decorated with transition metals |
|
| Single‐Bonded Cubic AsN from High‐Pressure and High‐Temperature Chemical Reactivity of Arsenic and Nitrogen |
|
| Synthesis of New Ruthenium‐CAP Complexes and Use as Catalysts for Benzonitrile Hydration to Benzamide |
|
| 2D exfoliated black phosphorus influences healthy and cancer prostate cell behaviors |
|
| Unraveling the Role of Metal Oxide Catalysts in the CO2 Desorption Process from Nonaqueous Sorbents: An Experimental Study Carried out with 13C NMR |
|
| Incorporation of 2D black phosphorus (2D-bP) in P3HT/PMMA mixtures for novel materials with tuned spectroscopic, morphological and electric features |
|
| Recent Advances in Metal Catalyst Design for CO<sub>2</sub> Hydroboration to C1 Derivatives |
|
| Air Stable Nickel-Decorated Black Phosphorus and Its Room-Temperature Chemiresistive Gas Sensor Capabilities |
|
| Interlayer Coordination of Pd-Pd Units in Exfoliated Black Phosphorus |
|
| Dispersion of Few-Layer Black Phosphorus in Binary Polymer Blend and Block Copolymer Matrices |
|
| Black Phosphorus n-Type Doping by Cu: A Microscopic Surface Investigation |
|
| Nickel-Decorated Black Phosphorus for Room Temperature NO2 Detection |
|
| Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex |
|
| Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs” |
|
| Catalysis Mediated by 2D Black Phosphorus Either Pristine or Decorated with Transition Metals Species |
|
| High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
|
| On the comparison of oxygen and sulfur transfer reactivities in phosphine and phosphorene: the case of R3Sb(X) carriers (X = O or S) |
|
| Mild and Selective Carbon Dioxide Hydroboration to Methoxyboranes Catalyzed by Mn(I) PNP Pincer Complexes |
|
| Nickel-Decorated Black Phosphorus for Room Temperature NO2 detection |
|
| Enhanced ambient stability of exfoliated black phosphorus by passivation with nickel nanoparticles |
|
| Diffusion NMR Studies on the Self-Aggregation of Ru-Arene CAP Complexes: Evidence for the Formation of H-Bonded Dicationic Species in Acetonitrile |
|
| Anisotropic thermal expansion of black phosphorus from nanoscale dynamics of phosphorene layers |
|
| High-Pressure Synthesis of Cyclic Phosphazenes by Near-UV Photoinduced Reactivity of NH<inf>3</inf> and Elemental Phosphorus |
|
| Nonclassical Longitudinal Magnetoresistance in Anisotropic Black Phosphorus |
|
| Epitaxial multilayers of alkanes on two-dimensional black phosphorus as passivating and electrically insulating nanostructures |
|
| H<inf>2</inf> production from lightweight inorganic hydrides catalyzed by 3d transition metals |
|
| Ammonia borane and hydrazine bis(borane) dehydrogenation mediated by an unsymmetrical (PNN) ruthenium pincer hydride: metal–ligand cooperation for hydrogen production |
|
| Metal-free carbon-based materials for electrocatalytic and photo-electrocatalytic CO2 reduction |
|
| Phosphorene and Black Phosphorus: The P-31 NMR View |
|
| Black Phosphorus/Palladium Nanohybrid: Unraveling the Nature of P-Pd Interaction and Application in Selective Hydrogenation |
|
| Noncovalent Functionalization of 2D Black Phosphorus with Fluorescent Boronic Derivatives of Pyrene for Probing and Modulating the Interaction with Molecular Oxygen |
|
| Metal-Assisted Opening of Intact P 4 Tetrahedra |
|
| A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices |
|
| Ruthenium mediated halogenation of white phosphorus: synthesis and reactivity of the unprecedented P4Cl2 moiety |
|
| Comparative Study of CO2 Capture by Aqueous and Nonaqueous 2-Amino-2-methyl-1-propanol Based Absorbents Carried Out by C-13 NMR and Enthalpy Analysis |
|
| Exfoliated Black Phosphorus Promotes in Vitro Bone Regeneration and Suppresses Osteosarcoma Progression through Cancer-Related Inflammation Inhibition |
|
| Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions |
|
| STM study of exfoliated few layer black phosphorus annealed in ultrahigh vacuum |
|
| Preface |
|
| Modelling strategies for the covalent functionalization of 2D phosphorene |
|
| Dual properties of water-soluble Ru-PTA complexes of dendrimers: Catalysis and interaction with DNA |
|
| The p-sc structure in phosphorus: bringing order to the high pressure phases of group 15 elements |
|
| Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance |
|
| Hybrid nanocomposites of 2D black phosphorus nanosheets encapsulated in PMMA polymer material: new platforms for advanced device fabrication |
|
| Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by C-13 NMR spectroscopy |
|
| Water-Soluble Silver(I) Complexes Featuring the Hemilabile 3,7-Dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization, and Antimicrobial Activity |
|
| Spray-loading: A cryogenic deposition method for diamond anvil cell |
|
| Phosphorus oxide gate dielectric for black phosphorus field effect transistors |
|
| Mechanistic Studies on NaHCO<inf>3</inf> Hydrogenation and HCOOH Dehydrogenation Reactions Catalysed by a Fe<sup>II</sup> Linear Tetraphosphine Complex |
|
| Polymer-Based Black Phosphorus (bP) Hybrid Materials by in Situ Radical Polymerization: An Effective Tool To Exfoliate bP and Stabilize bP Nanoflakes |
|
| Influence of highly basic phosphine ligand on the reactivity and hydrolysis of P<inf>4</inf> and P<inf>4</inf>S<inf>3</inf> supported by ruthenium fragments |
|
| Ruthenium(II)-arene complexes of the water-soluble ligand CAP as catalysts for homogeneous transfer hydrogenations in aqueous phase |
|
| More about the redox behavior of late transition metal triple-decker complexes with cyclo-triphosphorus |
|
| Preface |
|
| Dual properties of water-soluble Ru-PTA complexes of dendrimers: catalysis and interaction with DNA |
|
| Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications |
|
| The atomic level mechanism of white phosphorous demolition by di-iodine |
|
| CO2 capture by aqueous Na2CO3 integrated with high-quality CaCO3 formation and pure CO2 release at room conditions |
|
| Interlayer Bond Formation in Black Phosphorus at High Pressure |
|
| Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(mu(2)-dppm)(2)Cu-2((2)-BH4)(2)] Dichloromethane Solvate |
|
| Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ<sup>3</sup>-P-CH<inf>3</inf>C(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}RuH(η<sup>2</sup>-BH<inf>4</inf>)] |
|
| Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis |
|
| Phosphorene meets metal fragments |
|
| Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes |
|
| Novel water-free biphasic absorbents for efficient CO2 capture |
|
| New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent |
|
| Ammonia Borane Dehydrogenation Catalyzed by (kappa(4)-EP3)Co(H) [EP3 = E(CH2CH2PPh2)(3); E = N, P] and H-2 Evolution from Their Interaction with NH Acids |
|
| Metal-free reduction of phosphine oxides using polymethylhydrosiloxane |
|
| O-eugenol: A versatile molecule for production of polyfunctional alkenes via organometallic catalysis |
|
| Two pathways of proton transfer reaction to (triphos)Cu(η<sup>1</sup>-BH<inf>4</inf>): Via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane] |
|
| An active, stable and recyclable Ru(II) tetraphosphine-based catalytic system for hydrogen production by selective formic acid dehydrogenation |
|
| A straightforward access to ruthenium-coordinated fluorophosphines from phosphorous oxyacids |
|
| Dephasing in strongly anisotropic black phosphorus |
|
| Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold |
|
| Novel polystyrene-based nanocomposites by phosphorene dispersion |
|
| Reactions of the Lithiated Diphosphine tBu<inf>2</inf>P–P(SiMe<inf>3</inf>)Li with [(η<sup>6</sup>-C<inf>6</inf>H<inf>6</inf>)RuCl<inf>2</inf>]<inf>2</inf>in the Presence of Tertiary Phosphines |
|
| Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides |
|
| A Comparative Study of the CO2 Absorption in Some Solvent-Free Alkanolamines and in Aqueous Monoethanolamine (MEA) |
|
| Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands |
|
| Zinc Coordination Polymers Containing the m-(2-thiazolyl)benzoic Acid Spacer: Synthesis, Characterization and Luminescent Properties in Aqueous Solutions |
|
| Carbon dioxide uptake as ammonia and amine carbamates and their efficient conversion into urea and 1,3-disubstituted ureas |
|
| Dihydrogen Bonding and Proton Transfer from MH and OH Acids to Group 10 Metal Hydrides [((PCP)-P-tBu)MH] [(PCP)-P-tBu = kappa(3)-2,6-(tBu(2)PCH(2))(2)C6H3; M = Ni, Pd] |
|
| The Role of Water in the Preparation and Stabilization of High-Quality Phosphorene Flakes |
|
| Cooperative effects of ruthenium micellar catalysts and added surfactants in transfer hydrogenation of ketones in water |
|
| New wind in old sails: Novel applications of triphos-based transition metal complexes as homogeneous catalysts for small molecules and renewables activation |
|
| Thiazolo[5,4-d]thiazole-based organic sensitizers with strong visible light absorption for transparent, efficient and stable dye-sensitized solar cells |
|
| Two New Dyes with Carboxypyridinium Regioisomers as Anchoring Groups for Dye-Sensitized Solar Cells |
|
| Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands |
|
| Preface to the cluster issue: Advances in transition metal catalysis |
|
| A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process |
|
| Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation |
|
| Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation |
|
| Organic dyes with intense light absorption especially suitable for application in thin-layer dye-sensitized solar cells |
|
| The quest for hydrogen bond- based metal organic nanotubes MONT) |
|
| Synthesis, reactivity and catalytic properties of the allenylidene [Ru(C=C=CPh2)Cp(PTA)(PPh3)](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| [PF<inf>6</inf>]<inf>2</inf> As catalyst for the meyer-schuster rearrangement of arylpropargylic alcohols under mild conditions |
|
| Cross-coupling reactions: Some applications to the synthesis of thiazolothiazole- and benzobisthiazole-based dyes for new generation solar cells (DSSC) |
|
| Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution |
|
| Chemical Hydrogen Storage: Ammonia Borane Dehydrogenation Catalyzed by NP<inf>3</inf> Ruthenium Hydrides (NP<inf>3</inf>=N(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>) |
|
| A comparison of carboxypyridine isomers as sensitizers for dye-sensitized solar cells: assessment of device efficiency and stability |
|
| Electronic aspects of the phosphine-oxide -> phosphinous acid tautomerism and the assisting role of transition metal centers |
|
| The bimetallic activation of white phosphorus by trans-[RhCl(CO)(dppm)] <inf>2</inf> results in a Tetrahedro-Rh<inf>2</inf>P<inf>2</inf> Moiety |
|
| Reactivity of Diimido Complexes of Molybdenum and Tungsten towards Lithium Derivatives of Diphosphanes and Triphosphanes |
|
| 1D and 2D thiazole-based copper(II) coordination polymers: Synthesis and applications in carbon dioxide capture |
|
| Unraveling the mechanism of the ruthenium assisted hydrolysis of white phosphorus |
|
| Chemical curing in alkyd paints: An evaluation via FT-IR and NMR spectroscopies |
|
| Dihydrogen bonding in complex (PP<inf>3</inf>)RuH(η<sup>1</sup>-BH <inf>4</inf>) featuring two proton-accepting hydride sites: Experimental and theoretical studies |
|
| Transfer hydrogenation of ketones catalyzed by surface-active ruthenium and rhodium complexes in water |
|
| Bifunctional metallodendrimers based on AB<inf>5</inf> derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions Metallodendrimers Special Issue |
|
| Lower- and upper-rim-modified derivatives of 1,3,5-triaza-7-phosphaadamantane: Coordination chemistry and applications in catalytic reactions in water |
|
| Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: A combined experimental and DFT analysis of the reaction mechanism |
|
| Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP3 |
|
| High-pressure chemistry of red phosphorus and water under near-UV irradiation |
|
| Stabilization of the triphosphallyl ligand η<sup>3</sup>-P <inf>3</inf>{P(O)H} at iridium via alkaline activation of P<inf>4</inf> |
|
| Inner- versus Outer-Sphere Ru-Catalyzed Formic Acid Dehydrogenation: A Computational Study |
|
| Interaction between a transition-metal fluoride and a transition-metal hydride: Water-mediated hydrofluoric acid evolution following fluoride solvation |
|
| Erratum: Organic chromophores based on a fused bis-thiazole core and their application in dye-sensitized solar cells (European Journal of Organic Chemistry) |
|
| Water-Soluble, 1,3,5-Triaza-7-phosphaadamantane-Stabilized Palladium Nanoparticles and their Application in Biphasic Catalytic Hydrogenations at Room Temperature |
|
| Efficient CO2 absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP) |
|
| An unusual thiazolo[5,4-d]thiazole sensitizer for dye-sensitized solar cells |
|
| Organic Chromophores Based on a Fused Bis-Thiazole Core and Their Application in Dye-Sensitized Solar Cells |
|
| Assessment of new gem-silanediols as suitable sensitizers for dye-sensitized solar cells |
|
| Synthesis, characterization and CO<inf>2</inf> uptake of a chiral Co(ii) metal-organic framework containing a thiazolidine-based spacer |
|
| Novel Synthetic Pathways for Bis(acyl)phosphine Oxide Photoinitiators |
|
| Iodine activation of coordinated white phosphorus: Formation and transformation of 1,3-dihydride-2-iodidecyclotetraphosphane |
|
| Amine-templated polymeric Mg formates: crystalline scaffolds exhibiting extensive hydrogen bonding |
|
| Erratum: Experimental evidence of phosphine oxide generation in solution and trapping by ruthenium complexes (Angewandte Chemie - International Edition (2011) 50 (5370-5373) DOI: 10.1002/anie.201100822) |
|
| Synthesis and Characterization of Terminal [Re(XCO)(CO)(2)(triphos)] (X=N, P): Isocyanate versus Phosphaethynolate Complexes |
|
| Solution and solid-state dynamics of metal-coordinated white phosphorus |
|
| Improved Solvent Formulations for Efficient CO2 Absorption and Low-Temperature Desorption |
|
| The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis |
|
| Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties? |
|
| Amine-Templated Polymeric Lanthanide Formates: Synthesis, Characterization, and Applications in Luminescence and Magnetism |
|
| Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond |
|
| Electron-poor rhenium allenylidenes and their reactivity toward phosphines: A combined experimental and theoretical study |
|
| Nickel(II) hydride and fluoride pincer complexes and their reactivity with Lewis acids BX3 center dot L ( X = H, L = thf; X = F, L = Et2O) |
|
| Acid-base interaction between transition-metal hydrides: Dihydrogen bonding and dihydrogen evolution |
|
| From greenhouse gas to feedstock: formation of ammonium carbamate from CO2 and NH3 in organic solvents and its catalytic conversion into urea under mild conditions |
|
| Experimental Evidence of Phosphine Oxide Generation in Solution and Trapping by Ruthenium Complexes |
|
| Supramolecularly controlled surface activity of an amphiphilic ligand. Application to aqueous biphasic hydroformylation of higher olefins |
|
| Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P <inf>4</inf> ligand |
|
| Societe Chimique de France 2011 Prize Winners |
|
| Design and synthesis of thiazole and thiazolidine metallo-supramolecular networks |
|
| Imidazolyl-PTA derivatives as water-soluble (P,N) ligands for ruthenium-catalyzed hydrogenations |
|
| Hydrogen uptake by {H[Mg(HCOO)<inf>3</inf>]⊃NHMe<inf>2</inf>} <inf>∞</inf> and determination of its H<inf>2</inf> adsorption sites through monte carlo simulations |
|
| A 13C NMR investigation of CO2 absorption and desorption in aqueous 2,2'-iminodiethanol and N-methyl-2,2'-iminodiethanol |
|
| Iridium(I) complexes of upper rim functionalized PTA derivatives. Synthesis, characterization, and use in catalytic hydrogenations (PTA = 1,3,5-Triaaza-7-phosphaadamantane) |
|
| Coordination chemistry of thiazole-based ligands: New complexes generating 3D hydrogen-bonded architectures |
|
| Selective synthesis of 2-substituted 4-carboxy oxazoles, thiazoles and thiazolidines from serine or cysteine amino acids |
|
| Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA |
|
| Rhenium allenylidenes and their reactivity toward phosphines: A theoretical study |
|
| Comparative DFT analysis of ligand and solvent effects on the mechanism of H<inf>2</inf> activation in water mediated by half-sandwich complexes [Cp′Ru(PTA)<inf>2</inf>Cl] (Cp′ = C<inf>5</inf>H<inf>5</inf>, C <inf>5</inf>Me<inf>5</inf>; PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| D<sup>6</sup> metal systems for white phosphorus activation |
|
| P-4 Activation by Late-Transition Metal Complexes |
|
| Continuous cycles of CO2 absorption and amine regeneration with aqueous alkanolamines: a comparison of the efficiency between pure and blended DEA, MDEA and AMP solutions by C-13 NMR spectroscopy |
|
| Rationalization of the inhibition activity of structurally related organometallic compounds against the drug target cathepsin B by DFT |
|
| Mechanistic studies on the interaction of [(κ<sup>3</sup>- P, P, P -NP<inf>3</inf>)IrH<inf>3</inf>] [NP<inf>3</inf> = N(CH<inf>2</inf>CH <inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>] with HBF<inf>4</inf> and Fluorinated Alcohols by Combined NMR, IR, and DFT Techniques |
|
| Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications |
|
| Coordination and reactivity of white phosphorus and tetraphosphorus trisulphide in the presence of the fragment CpFe(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] |
|
| New highly water-soluble rhodium complexes bearing 1,3,5-triaza-7-phosphaadamantane (PTA) and/or tris(hydroxymethyl)phosphine (THP) |
|
| Synthesis, characterization and hydrolysis of osmium tetraphosphorus complexes |
|
| Cyclopentadienyl ruthenium(II) complexes with bridging alkynylphosphine ligands: Synthesis and electrochemical studies |
|
| A C-13 NMR study of the carbon dioxide absorption and desorption equilibria by aqueous 2-aminoethanol and N-methyl-substituted 2-aminoethanol |
|
| Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media |
|
| Insertion of CO and strained olefins into organometallic (ferrocenylmethyl)phosphane palladium complexes |
|
| Reactivity of [TpRuCl(PTA)(PPh<inf>3</inf>)] with alkynes and propargylic alcohols: Occurrence of structurally related cationic vs neutral allenylidene complexes with the ruthenium hydrotris(pyrazolyl)borate moiety |
|
| The italian chemical society is 100 years old |
|
| Selective B-H versus N-H bond activation in ammonia borane by [Ir(dppm)<inf>2</inf>]OTf |
|
| Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated β-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives |
|
| Synthesis and characterization of new rhodium and iridium complexes with trianisylphosphine, PAn<inf>3</inf>, and evaluation of their catalytic behavior in the homogeneous hydrogenation of cinnamaldehyde |
|
| Influence of Structural Variation on the Anticancer Activity of RAPTA-Type Complexes: ptn versus pta |
|
| Getting a Clue to the Hydrolytic Activation of White Phosphorus: The Generation and Stabilization of P(OH)(2)PHPHPH(OH) at Ruthenium Centers |
|
| Reactivity of mononuclear Pd(ii) and Pt(ii) complexes containing the primary phosphane (ferrocenylmethyl)phosphane towards metal chlorides and PPh<inf>3</inf> |
|
| Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catena-phosphonium(+)diphosphenide(-) ligands |
|
| Controlling the activation of white phosphorus: Formation of phosphorous acid and ruthenium-coordinated 1-hydroxytriphosphane by hydrolysis of doubly metalated P-4 |
|
| The role of zinc(II) in the absorption-desorption of CO2 by aqueous NH3, a potentially cost-effective method for CO2 capture and recycling |
|
| Synthesis of dendrimers terminated by bis(diphenylphosphinomethyl)amino ligands and use of their palladium complexes for catalyzing C-C cross-coupling reactions |
|
| NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph <inf>2</inf>PCH<inf>2</inf>PPh<inf>2</inf>PPPP) {Pt(PPh<inf>3</inf>) <inf>2</inf>}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus |
|
| Phase transitions and CO2 adsorption properties of polymeric magnesium formate |
|
| Reactivity of thiophosphinous acid bound to ruthenium |
|
| Synthesis and characterisation of κ<sup>1</sup>-P and κ<sup>2</sup>-P,N palladium(II) complexes of the open cage water soluble aminophosphine PTN |
|
| Synthesis and reactivity of rhodium(III) pentamethylcyclopentadienyl complexes of N-B-PTA(BH<inf>3</inf>): X-ray crystal structures of [Cp<sup>*</sup>RhCl<inf>2</inf>{N-B}-PTA(BH<inf>3</inf>)] and [Cp<sup>*</sup>Rh{N-B-PTA(BH<inf>3</inf>)}(η<sup>2</sup>-CH<inf>2</inf> = CHPh)] |
|
| Combined process of CO<inf>2</inf> capture by potassium carbonate and production of basic zinc(II) carbonates: CO<inf>2</inf> release from bicarbonate solutions at room temperature and pressure |
|
| Oxidation of thiophene derivatives with H<inf>2</inf>O<inf>2</inf> in acetonitrile catalyzed by [Cp*<inf>2</inf>M<inf>2</inf>O<inf>5</inf>] (M = Mo, W): A kinetic study |
|
| PGSE NMR studies on RAPTA derivatives: Evidence for the formation of H-bonded dicationic species |
|
| INOR 167-Efficient oxidation of thiophene derivatives catalyzed by organomolybdenum and -tungsten oxido complexes |
|
| Dynamic behaviour of the [(triphos)Rh(eta(1):eta(2)-P4RR ')](n+) complexes [triphos = MeC(CH2PPh2)(3); R = H, alkyl, aryl; R ' = lone pair, H, Me; n=0, 1]: NMR and computational studies |
|
| (Pentamethylcyclopentadienyl)iridium-PTA (PTA=1,3,5-triaza-7-phosphaadamantane) complexes and their application in catalytic water phase carbon dioxide hydrogenation |
|
| Bimetallic activation of white phosphorus |
|
| Diastereomerically enriched analogues of the water-soluble phosphine PTA. Synthesis of phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.1<sup>3,7</sup>]dec-6- yl)methanol (PZA) and the sulfide PZA(S) and X-ray crystal structures of the oxide PZA(O) and [Cp*IrCl<inf>2</inf>(PZA)] |
|
| Hydrolysis of dinuclear ruthenium complexes [{CpRu(PPh<inf>3</inf>) <inf>2</inf>}<inf>2</inf>(μ,η<sup>1:1</sup>-L)]-[CF<inf>3</inf>so <inf>3</inf>]<inf>2</inf> (L = P<inf>4</inf>, P<inf>4</inf>S<inf>3</inf>): Simple access to metal complexes of P<inf>2</inf>H<inf>4</inf> and PH <inf>2</inf>SH |
|
| DNA interactions mediated by cyclopentadienidoruthenium(II) complexes containing water-soluble phosphanes |
|
| Synthesis, reactivity, X-ray crystal structures and electrochemical behaviour of water-soluble [tris(pyrazolyl)borato]ruthenium(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) |
|
| Asymmetric hydroformylation of olefins with Rh catalysts modified with chiral phosphine-phosphite ligands |
|
| Aqueous phase carbon dioxide and bicarbonate hydrogenation catalyzed by cyclopentadienyl ruthenium complexes |
|
| Specific and non-specific influence of the environment on dihydrogen bonding and proton transfer to [RuH2{P(CH2CH2PPh2)(3)}] |
|
| Electro-oxidation of ruthenium cyclopentadienyl PTA complexes in DMF |
|
| EcoTILLING for the identification of allelic variants of melon elF4E, a factor that controls virus susceptibility |
|
| From vegetable residues to hydrogen and electric power: Feasibility of a two step process operating with purple non sulfur bacteria |
|
| Synthesis of new enantiomerically enriched β-hydroxy-γ-amino phosphines by selective transformation of naturally occurring amino acids |
|
| INOR 783-Plane hydrolysis of coordinated phosphorus and phosphorus sulphide |
|
| Water-assisted H - H bond splitting mediated by [CpRu(PTA)<inf>2</inf>Cl] (PTA=1,3,5-triaza-7-phosphaadamantane). A DFT analysis |
|
| Oxidation of white phosphorus by peroxides in aqueous and alcoholic solutions: mechanistic aspects and catalytic studies |
|
| Reactivity of rhodium(I) iminophosphine carbonyl complexes with methyl Iodide |
|
| Highly efficient asymmetric hydrogenation of alkyl aryl ketones catalyzed by iridium complexes with chiral planar ferrocenyl phosphino-thioether ligands |
|
| Reduced number of steps for the synthesis of dense and highly functionalized dendrimers |
|
| A ligand-driven geometry switch in octahedral and trigonal-bipyramidal iron complexes containing (H)PNO and PNN ligands |
|
| CO2 absorption by aqueous NH3 solutions: speciation of ammonium carbamate, bicarbonate and carbonate by a C-13 NMR |
|
| A snapshot of P<inf>4</inf> tetrahedron opening: Rh- and Ir-mediated activation of white phosphorus |
|
| Stabilization of the tautomers HP(OH)<inf>2</inf> and P(OH)<inf>3</inf> of hypophosphorous and phosphorous acids as ligands |
|
| Ruthenium catalyzed selective oxidation of aryl thiophenes using hydrogen peroxide |
|
| Hydrolytic disproportionation of coordinated white phosphorus in [CpRu(dppe)(η<sup>1</sup>-P<inf>4</inf>)]PF<inf>6</inf> [dppe = 1,2-bis(diphenylphosphino)ethane] |
|
| Reactivity of (ferrocenylmethyl)phosphine toward palladium and platinum chlorides. X-ray structure of [Pd(PH<inf>2</inf>CH<inf>2</inf>Fc)Cl(μ- PHCH<inf>2</inf>Fc)]<inf>4</inf> (Fc = ferrocenyl), a unique complex containing a Pd<inf>4</inf>P<inf>4</inf> Cycle |
|
| In vitro evaluation of rhodium and osmium RAPTA analogues: The case for organometallic anticancer drugs not based on ruthenium |
|
| Octahedral Ru<sup>II</sup> complexes with [PNO] hydrazonic ligands: Synthesis, structure, reactivity and catalytic activity in the addition of benzoic acid to alkynes |
|
| Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| A new class of rhodium(I) κ.<sup>1</sup>-P and κ<sup>2</sup>-P, N complexes with rigid PTN(R) ligands (PTN = 7-phospha-3-methyl-1,3,5- triazabicyclo[3.3.1]nonane) |
|
| Synthesis, characterization and reactivity of tribenzylphosphine rhodium and iridium complexes |
|
| Synthesis, Characterization, and DNA Binding of New Water-Soluble Cyclopentadienyl Ruthenium(II) Complexes Incorporating Phosphines |
|
| Synthesis, characterization, protonation studies and X-ray crystal structure of ReH<inf>5</inf>(PPh<inf>3</inf>)<inf>2</inf>(PTA) (PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| Imine hydrogenation by tribenzylphosphine rhodium and iridium complexes |
|
| Synthesis of heterocyclic ligands by diheterocyclization at the rhenium(I) allenylidene [(triphos)(CO)<inf>2</inf>Re{C=C=CPh<inf>2</inf>}](OSO <inf>2</inf>CF<inf>3</inf>). 1. Reactivity with dipolar N,N-heterocycles |
|
| Amino-phosphanes in Rh<sup>I</sup>-catalyzed hydroformylation: Hemilabile behavior of P,N ligands under high CO pressure and catalytic properties |
|
| Easy hydrolysis of white phosphorus coordinated to ruthenium |
|
| From P-4 to PH3 Metal Complexes by Plane Hydrolysis |
|
| Synthesis and X-ray Study of the P-5-polyphosphorus Rhodium Complex [(dppm){Ph2PCH2P(Ph-2)PPPP}Rh]OTf |
|
| Coordination chemistry and functionalization of white phosphorus via transition metal complexes |
|
| On the protonation of ruthenium-PTA complexes in water. X-ray crystal structure of RuCl<inf>4</inf>(PTAH)<inf>2</inf>·4 H<inf>2</inf>O (PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| Ruthenium-promoted Z-selective head-to-head dimerization of terminal alkynes in organic and aqueous media |
|
| Stable, water-soluble Pta-based Ru-Ag organometallic polymers |
|
| Adducts of cyclotriphosphorus complexes with cyclopentadienyl ruthenium fragments: Synthesis, solid-state structure and solution behaviour |
|
| Synthesis, characterization, and electrochemical behavior Of mono- and bimetallic ruthenium and rhenium allenylidenes bearing multiconjugated organic spacers |
|
| Rhenium(III) and technetium(III) complexes with 2-mercapto-1,3-azole ligands and X-ray crystal structures |
|
| Synthesis, characterisation and molecular structure of Re(III) 2-oxacyclocarbenes stabilised by a benzoyldiazenido ligand |
|
| Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA): Transition metal complexes and related catalytic, medicinal and photoluminescent applications |
|
| Ruthenium(II) π-alkyne and vinylidene complexes derived from glycoynitols: New precursors for water-soluble unsaturated carbenes |
|
| Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA = 1,3,5-triaza-7-phosphaadamantane) |
|
| Functionalization of white phosphorus in the coordination sphere of transition metal complexes |
|
| Activation of molecular hydrogen over a binuclear complex with Rh <inf>2</inf>S<inf>2</inf> core: DFT calculations and NMR mechanistic studies |
|
| Reaction of [CpRu(CH<inf>3</inf>CN)<inf>3</inf>]PF<inf>6</inf> with bidentate ligands: Structural characterization of [{CpRu(CH<inf>3</inf>CN)<inf>2</inf>}<inf>2</inf> (μ-η<sup>1:1</sup>-dppe)](PF<inf>6</inf>)<inf>2</inf> [dppe=1,2-bis(diphenylphosphino)ethane] |
|
| ν<sup>1</sup>-P<inf>basal</inf> Coordination of P<inf>4</inf>X <inf>3</inf> (X = S, Se) Molecules toward 16e Ruthenium Fragments |
|
| Bonding isomerism in the η<sup>1</sup>-P coordination of the P<inf>4</inf>X<inf>3</inf> (X=S, Se) molecules toward 16e rhodium fragments stabilized by tripodal tetradentate ligands |
|
| Nucleophilic addition of phosphines to rhenium allenylidenes. Unprecedented double P–H bond activation to give an η<sup>1</sup>-P-phospha-1-butadienyl ligand |
|
| Tetrahedral cobalt(II) complexes stabilized by the aminodiphosphine PNP ligand [PNP = CH<inf>3</inf>CH<inf>2</inf>CH<inf>2</inf>N-(CH<inf>2</inf> CH<inf>2</inf>PPh<inf>2</inf>)<inf>2</inf>] |
|
| Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)(2)] (R = H, Me; PTA=1,3,5-triaza-7-phosphaadamantane) |
|
| Activation and functionalization of white phosphorus at rhodium: Experimental and computational analysis of the [(triphos)Rh (eta(1):eta(2)-P4RR ')]Y complexes (triphos = MeC(CH2PPh2)(3); R = H, alkyl, aryl; R '=2 electrons, H, Me) |
|
| Ruthenium-catalysed selective transetherification of substituted vinyl ethers to form acetals and aldehydes |
|
| How can the metal affect the proton transfer to the dihydrides [{P(CH <inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}MH<inf>2</inf>] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study |
|
| Low-temperature IR and NMR studies of the interaction of group 8 metal dihydrides with alcohols |
|
| Transition-metal-mediated activation and functionalization of white phosphorus and related molecules |
|
| 1,3-Cycloaddition of pyrazole to the allenylidene ligand in [Re{C=C=CPh<inf>2</inf>}(CO)<inf>2</inf>{MeC(CH<inf>2</inf>PPh<inf>2</inf>) <inf>3</inf>}]<sup>+</sup> |
|
| Metal-mediated degradation and reaggregation of white phosphorus |
|
| Unprecedented η<sup>1</sup>-P<inf>basal</inf> coordination of P<inf>4</inf>X<inf>3</inf> molecules (X = S, Se). An experimental and theoretical study of the apical vs basal complexation dichotomy |
|
| Synthesis and chemistry of 2-oxacyclocarbene and 2-cyclovinyl ether ligands supported by the [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re(CO)<inf>2</inf>] <sup>+</sup> auxiliary |
|
| η<sup>1</sup>-P<inf>apical</inf> and η<sup>1</sup>-P<inf>basal</inf> coordination of the P<inf>4</inf>X<inf>3</inf> (x = S, Se) molecules toward 16-e metal fragments |
|
| Synthesis and structural characterization of (carbene)ruthenium complexes binding nucleobases |
|
| Synthesis, characterization, and interconversion of the rhenium polyhydrides [ReH3(eta(4)-NP3)] and [ReH4(eta(4)-NP3)](+) {NP3 = tris[2-(diphenylphosphanyl)-ethyl]amine} |
|
| Addition of E-H bonds (E = S, N) across the C<inf>α</inf>=C<inf>β</inf> bond of the allenylidene ligand in [Re{C=C=CPh<inf>2</inf>}(CO)<inf>2</inf>(triphos)](OSO<inf>2</inf>CF<inf>3</inf> ) (triphos = MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>) |
|
| Rhenium(III) and rhenium(V) complexes stabilized by the potentially tetradentate ligand tris(2-diphenylphosphinoethyl)amine |
|
| Ligand and solvent effects in the alternating copolymerization of carbon monoxide and olefins by palladium-diphosphine catalysis |
|
| Synthesis, characterization, and interconversion of the rhenium polyhydrides [ReH<inf>3</inf>(η<sup>4</sup>-NP<inf>3</inf>)] and [ReH<inf>4</inf>(η<sup>4</sup>-NP<inf>3</inf>)]+ {NP<inf>3</inf> = tris[2-(diphenylphosphanyl)-ethyl]amine} |
|
| Synthesis of exceptionally stable iron and ruthenium eta1-tetrahedro-tetraphosphorus complexes: Evidence for a strong temperature dependence of M-P4 pi back donation |
|
| Activation of 2-propyn-1-ols by the rhenium(I) fragment [{MeC(CH2PPh2)(3)}Re(CO)(2)](+). Synthesis and characterization of cationic Re(I) complexes containing unsaturated eta(1)-carbon ligands |
|
| Backward synthesis of rhenium(I) γ3-hydroxyvinylidene and γ-methoxyvinylidene complexes and their conversion to the allenylidene[Re{C=C=CPh<inf>2</inf>}(CO)<inf>2</inf>(MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>)](OSO<inf>2</inf>CF<inf>3</inf>) |
|
| In-depth NMR and IR study of the proton transfer equilibrium between [{(MeC(CH2PPh2)(3)}Ru(CO)H-2] and hexafluoroisopropanol |
|
| Backward synthesis of rhenium(I) γ3-hydroxyvinylidene and γ-methoxyvinylidene complexes and their conversion to the allenylidene[Re{C=C=CPh<inf>2</inf>}(CO)<inf>2</inf>(MeC(CH<inf>2</inf>PPh <inf>2</inf>)<inf>3</inf>)](OSO<inf>2</inf>CF<inf>3</inf>) |
|
| In-depth NMR and IR study of the proton transfer equilibrium between [{(MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Ru(CO)H<inf>2</inf>] and hexafluoroisopropanol |
|
| Reactivity of the P<inf>4</inf> molecule with cobalt(I) and rhodium(I) polyphosphane fragments |
|
| The energy profile of proton transfer from brønsted acids to terminal hydrides in transition metal complexes can be estimated by combining in situ IR and NMR spectroscopy |
|
| Water-soluble ruthenium vinylidene and allenylidene complexes: Potential catalysts for ring-opening metathesis |
|
| Ruthenium-assisted synthesis of gem-deuterated alkenes from monosubstituted propargyl alcohols and D<inf>2</inf>O |
|
| Reaction of [(PPh<inf>3</inf>)<inf>3</inf>RuCl<inf>2</inf>] with white phosphorus: Synthesis of the first Ru<sup>II</sup>complex featuring a tetrahedro-tetraphosphorus ligand |
|
| Platinum-mediated oxidative P-O coupling of white phosphorus and alcohols: An ab initio study |
|
| Cyclotriphosphorus complexes: Solid-state structures and dynamic behavior of monoadducts with carbonyl fragments |
|
| <sup>1</sup>H- and <sup>2</sup>H-T<inf>1</inf> relaxation behavior of the rhodium dihydrogen complex [(triphos)Rh(η<sup>2</sup>-H<inf>2</inf>)H<inf>2</inf>]<sup>+</sup> |
|
| Adducts of cyclotriphosphorus complexes: Synthesis, solid state structure and solution behaviour of the bis-adducts [{(triphos)Co}(P<inf>3</inf>){M(CO)<inf>5</inf>}<inf>2</inf>] [triphos=MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>; M=Cr, Mo, W] |
|
| Reaction of [(PPh<inf>3</inf>)<inf>3</inf>RuCl<inf>2</inf>] with white phosphorus: Synthesis of the first Ru<sup>II</sup> complex featuring a tetrahedro-tetraphosphorus ligand |
|
| Addition of copper(I) and silver(I) to a P-P bond in [(triphos)MP3] [triphos=1,1,1- tris(diphenylphosphinomethyl)ethane; M=Co, Rh] - X-ray crystal structure of [{(triphos)CoP3}(2)Cu]PF6 |
|
| <sup>2</sup>H-T<inf>1</inf> relaxation and deuterium quadrupole coupling constants in transition metal η<sup>2</sup>-D<inf>2</inf> complexes |
|
| First Examples of Rhenium-Assisted Activation of Propargyl Alcohols: Allenylidene, Carbene, and Vinylidene Rhenium(I) Complexes |
|
| Rhodium-Mediated Functionalization of White Phosphorus: A Novel Formation of C-P Bonds |
|
| Synthesis and characterisation of tetrahedro-tetraphosphorus complexes of rhenium - Evidence for the first bridging complex of white phosphorus |
|
| Preface to the special issue (Part II) of Coordination Chemistry Reviews linked to the 33(rd) International Conference on Coordination Chemistry, August 30th-September 4th, 1998, Florence, Italy |
|
| Aminocarbene Complexes as Intermediates in the Ruthenium-Assisted Aminolysis of Phenylacetylene to Isonitriles and Toluene |
|
| Preface to the special issue (Part 1) of Coordination Chemistry reviews linked to the 33(rd) International Conference on Coordination Chemistry, August 30th-September 4th, 1998, Florence, Italy |
|
| Selective C(α)-C(β) bond cleavage by water in allenylidene and alkenylvinylidene ruthenium complexes |
|
| Substitution of labile triflate in [(triphos)Re(CO)<inf>2</inf>(OTf)]: A new synthetic route to mononuclear and dinuclear Re(I) complexes |
|
| Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium (II) |
|
| In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [{MeC(CH2PPh2)3}Re(CO)(2)H]. ReH center dot center dot center dot H bonding and proton-transfer pathways |
|
| Hydrogenation of white phosphorus to phosphane with rhodium and iridium trihydrides |
|
| The role of cyclo-triphosphorus (P<inf>3</inf>) in-plane σ orbitals in coordinating transition metal fragments |
|
| C-S bond cleavage of benzo[b]thiophene at ruthenium |
|
| Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II) |
|
| 2-oxacyclopentylidene, 2-oxacyclohexylidene, and 2-oxacycloheptylidene rhenium complexes by reaction of omega-alkynols with the [{MeC(CH2PPh2)(3)}Re(CO)(2)](+) auxiliary |
|
| 2-Oxacyclopentylidene, 2-oxacyclohexylidene, and 2-oxacycloheptylidene rhenium complexes by reaction of ω-alkynols with the [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re(CO)<inf>2</inf>]<sup>+</sup> auxiliary |
|
| In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re (CO)<inf>2</inf>H]. ReH⋯H bonding and proton-transfer pathways |
|
| Synthesis of the new chiral (R)- and (S)-aminodiphosphine ligands sec-butylbis(2-(diphenylphosphino)ethyl)amine, sec-butylbis(2-(dicyclohexylphosphino)ethyl)amine, and (α-methylbenzyl)bis(2-(dicyclohexylphosphino)ethyl)amine and their organometallic chemistry when combined with iridium |
|
| Synthesis and reactivity of the labile dihydrogen complex [{MeC(CH2PPh2)(3)}Ir(H-2)(H)(2)]BPh4 |
|
| 1-Hexene hydroformylation with the rhodium(I) triphosphane complex [Rh(CO){PhP(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>2</inf>}]PF <inf>6</inf>: An in situ study using high-pressure NMR spectroscopy |
|
| C-H bond cleavage in thiophenes by [P(CH2CH2PPh2)(3)Ru]. UV flash kinetic spectroscopy discloses the ruthenium-thiophene adduct which precedes C-H insertion |
|
| Synthesis of the new chiral (R)- and (S)-aminodiphosphine ligands sec-butylbis(2-(diphenylphosphino)ethyl)amine, sec-butylbis(2-(dicyclohexylphosphino)ethyl)amine and (alpha-methylbenzyl)bis(2-(dicyclohexylphosphino)ethyl)amine and their organometallic chemistry when combined with iridium |
|
| Photochemistry of M(PP<inf>3</inf>)H<inf>2</inf> (M = Ru, Os; PP<inf>3</inf> = P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>): Preparative, NMR, and time-resolved studies |
|
| Anodically-induced metal deprotonation of the hydride complexes [{PCH2CH2PPh2)(3)}M(H)Cl] (M=Fe, Ru, Os): The first step to the electrogeneration of Fe(I), Ru(I) and Os(I) five-coordinate complexes |
|
| Ab initio and experimental studies on the structure and relative stability of the cis-hydride-eta 2-dihydrogen complexes [{P(CH(2)CH(2)PPh(2))(3)}M(H)(eta(2)-H-2)](+) (M=Fe, Ru) |
|
| Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Ir(H<inf>2</inf>)(H) <inf>2</inf>]BPh<inf>4</inf> |
|
| C-H bond cleavage in thiophenes by [P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>Ru]. UV flash kinetic spectroscopy discloses the ruthenium-thiophene adduct which precedes C-H insertion |
|
| Anodically-induced metal deprotonation of the hydrido complexes [{PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}M(H)Cl] (M = Fe, Ru, Os): The first step to the electrogeneration of Fe(I), Ru(I) and Os(I) five-coordinate complexes |
|
| Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis-Hydride-η<sup>2</sup>-Dihydrogen Complexes [{P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}M (H)(η<sup>2</sup>-H<inf>2</inf>)]<sup>+</sup> (M = Fe, Ru) |
|
| C-C bond formation between vinylidene and alkynyl ligands at ruthenium(II) leading to either enynyl or dienynyl complexes |
|
| The mechanism of the Ru-assisted C-C bond cleavage of terminal alkynes by water |
|
| anti,mer-[bis(2-diphenylphosphinoethyl)-(n-propyl)amine-N,P,P′] (phenylethynyl)-[(Z)-1-p-tolyl-4-phenyl-η <sup>3</sup>-but-1-en-3-ynyl]-ruthenium(II) chloroform solvate |
|
| C-C bend formation between vinylidene and alkynyl ligands at ruthenium(II) leading to either enynyl or dienynyl complexes |
|
| Multiple Re-C bonds at the [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re(CO)<inf>2</inf>]<sup>+</sup>auxiliary |
|
| anti,mer-[bis(2-diphenylphosphinoethyl)-(n-propyl)amine-N,P,P′] (phenylethynyl)-[(Z)-1-p-tolyl-4-phenyl-η <sup>3</sup>-but-1-en-3-ynyl]-ruthenium(II) chloroform solvate |
|
| Multiple Re-C bonds at the [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re(CO)<inf>2</inf>]<sup>+</sup> auxiliary |
|
| Role of transesophageal echocardiography in the evaluation of the potential embolic risk in left atrial thrombosis. Report of a clinical case,Ruolo dell'ecocardiografia transesofagea nella valutazione del potenziale rischio embolico della trombosi atriale sinistra. Descrizione di un caso clinico. |
|
| mer,trans-[bis(2-diphenylphosphino-ethyl)(n-propyl)amine-N,P,P']dichloro-(triphenylphosphine)ruthenium(II) 0.5-dichloromethane solvate |
|
| Ruthenium(II)-Mediated Reaction of Phenylacetylene with Primary Amines To Give Ruthenium(II)-Isonitrile Complexes |
|
| Reactions of the Rhenium(I) Fragment [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Re(CO)<inf>2</inf>]<sup>+</sup>. Synthesis and Characterization of a Stable Cationic η<sup>2</sup>-H<inf>2</inf>Complex of Rhenium |
|
| Thiophene C-S bond cleavage by rhodium and iridium. An unprecedented bridging mode of the open C<inf>4</inf>H<inf>4</inf>S fragment |
|
| A new P-chiral aminophosphine ligand containing a 2,2′-coupled pyrrolidine-phospholane ring system. Synthesis and coordination properties with rhodium(I) and iridium(I) fragments |
|
| Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(α-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of α,β-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis |
|
| Mechanistic Study of Ir(H)<inf>2</inf>-Assisted Transformations of Ethyne: Cyclotrimerization, Cooligomerization with Ethene, and Reductive Coupling |
|
| Chemoselective reduction of α,β-unsaturated ketones catalyzed by transition metal complexes with polydentate ligands |
|
| Control of the Bridgehead Donor Atom in the Tripodal Ligand over Oxidative Addition of Au(PPh<inf>3</inf>)<sup>+</sup> to [X(CH<inf>2</inf>CH<inf>2</inf>PPh2)3RhH] (X = N, P). X-ray Diffraction and Multinuclear (<sup>103</sup>Rh, <sup>31</sup>P, <sup>1</sup>H) NMR Studies |
|
| A novel reaction of coordinated vinylidenes: Coupling with hydrogen sulfide to give a η<sup>1</sup>-thioaldehyde |
|
| Regio- and Stereoselective Dimerization of Phenylacetylene to (Z)-1,4-Diphenylbut-3-en-1-yne by Ruthenium(II) Catalysis. Reaction Mechanism Involving Intermolecular Protonation of σ-Alkynyl by 1-Alkyne |
|
| A 5-COORDINATE RUTHENIUM(I) COMPLEX |
|
| Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(II) complex |
|
| MECHANISM OF ACETYLENE CYCLOTRIMERIZATION CATALYZED BY THE FAC-IRP3+ FRAGMENT - RELATIONSHIP BETWEEN FLUXIONALITY AND CATALYSIS |
|
| HDS MODEL SYSTEMS - COORDINATION, OPENING, AND HYDROGENATION OF BENZO[B]THIOPHENE AT IRIDIUM |
|
| HDS Model Systems. 2,3-Dihydrothiophene as an Intermediate in the Homogeneous Hydrogenation of Thiophene to Tetrahydrothiophene at Iridium |
|
| Pulsed laser photolysis of Os(pp<inf>3</inf>)H<inf>2</inf> [pp<inf>3</inf> = P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>]: Kinetic selectivity for reaction with methane |
|
| CHEMOSELECTIVE HYDROGEN-TRANSFER REDUCTION OF ALPHA,BETA-UNSATURATED KETONES CATALYZED BY ISOSTRUCTURAL IRON(II), RUTHENIUM(II), AND OSMIUM(II) CIS HYDRIDE ETA(2)-DIHYDROGEN COMPLEXES |
|
| Molecular Solid-Gas Organometallic Chemistry. Catalytic and Stoichiometric Transformations of Ethyne at Iridium |
|
| HYDRODESULFURIZATION MODEL SYSTEMS - HOMOGENEOUS AND HETEROGENEOUS (SOLID-GAS) HYDROGENATION OF BENZOTHIOPHENE AT IRIDIUM |
|
| Thermal and Photochemical CH Bond Activation Reactions at Iridium. π-Coordination vs CH Cleavage of Ethene, Styrene, and Phenylacetylene |
|
| Synthesis and characterization of rhenium polyhydrides stabilized by the tripodal ligand MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf> |
|
| CLASSICAL, NONCLASSICAL, AND MIXED-METAL OSMIUM(II) POLYHYDRIDES STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 - H/D ISOTOPE-EXCHANGE REACTIONS PROMOTED BY A STRONGLY BOUND DIHYDROGEN LIGAND |
|
| OPENING, DESULFURIZATION, AND HYDROGENATION OF THIOPHENE AT IRIDIUM - AN EXPERIMENTAL-STUDY IN A HOMOGENEOUS PHASE |
|
| A FAMILY OF STABLE IRON(I) SIGMA-ALKYNYL COMPLEXES - SYNTHESIS, CHARACTERIZATION, STRUCTURE, AND ELECTRON-TRANSFER CHEMISTRY |
|
| Reactivity of the [Re≡NR]<sup>3+</sup> and [Re≡N]<sup>2+</sup> cores toward bis(diphenylphosphino)amine and its derivatives. Synthesis and crystal structures |
|
| REACTIVITY OF RHENIUM(V) COMPLEXES CONTAINING DIFFERENT CORES SUCH AS [REO]3+, [RENR]3+ AND [REN]2+ TOWARD BIS(DIPHENYLPHOSPHINO)METHANE - SYNTHESIS AND CRYSTAL-STRUCTURES |
|
| Structure of (4‐pentynoato‐O,O'){tris[2‐(diphenylphosphino)ethyl]phosphine}iron(II) tetraphenylborate |
|
| A Deceptively Simple case of Selective Hydrogenation of Phenylacetylene to Styrene Catalyzed by a cis-Hydrido(η<sup>2</sup>-dihydrogen)ruthenium(II) Complex |
|
| DESIGNING HOMOGENEOUS CATALYSTS - RU(II) COMPLEXES WITH POLYDENTATE MIXED-P,N-DONOR LIGANDS |
|
| Tripodal polyphosphine ligands control selectivity of organometallic reactions |
|
| The Barrier to Rotation of the Dihydrogen Ligand in the Complexes [mh(η<sup>2</sup>-H<inf>2</inf>)PP<inf>3</inf>]BPh<inf>4</inf> (M = Fe, Ru): Evidence for Stronger Back-Donation in the Iron Complex |
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| Synthesis, Characterization, and Molecular Structure of the First Metal Complex Containing Thallium Chloride as a Ligand. A Novel Carrier of Thallium(I) |
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| Mixed Iridium-Gold Hydrides as Model Compounds for Elucidating the Interconversion between Classical and Nonclassical Polyhydrides |
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| Stepwise Metal-Assisted Reduction of η<sup>4</sup>-Coordinated Benzene to Cyclohexen |
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| REVERSIBLE UPTAKE OF H2 AND N2 AT COBALT IN THE SOLID-STATE - INFLUENCE OF THE COUNTER ANION ON THE FORMATION OF CLASSICAL DIHYDRIDE VS NONCLASSICAL ETA-2-DIHYDROGEN FORMS OF [(PP3)COH2]+ |
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| Reactivity of the [Re≡O]<sup>3+</sup> core toward Ph<inf>2</inf>P(Se)NH(Se)PPh<inf>2</inf> |
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| SELECTIVE HYDROGENATION OF 1-ALKYNES TO ALKENES CATALYZED BY AN IRON(II) CIS-HYDRIDE ETA-2-DIHYDROGEN COMPLEX - A CASE OF INTRAMOLECULAR REACTION BETWEEN ETA-2-H-2 AND SIGMA-VINYL LIGANDS |
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| SYNTHESIS AND CHARACTERIZATION OF AN IRON(II) CIS-HYDRIDE(ETA-2-DIHYDROGEN) COMPLEX STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 |
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| Crystal structure and reactivity of [(pp<inf>3</inf>)Rh(H)(SeCH<inf>3</inf>)]BPh<inf>4</inf>. An organometallic complex from metal-assisted SeH activation |
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| METAL HYDRIDE ALKYNYL -] METAL VINYLIDENE REARRANGEMENTS OCCURRING IN BOTH SOLID-STATE AND SOLUTION - ROLE OF THE 1-ALKYNE SUBSTITUENT IN DETERMINING THE RELATIVE STABILITY OF PI-ALKYNE, HYDRIDE ALKYNYL, AND VINYLIDENE FORMS AT COBALT |
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| Solid-State Organometallic Chemistry of Tripodal (Polyphosphine)metal Complexes. C-H Activation Reactions at Cobalt(I) Encapsulated into the Tetraphosphine P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf> |
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| Disproportionation of acyclic ketones to carboxylate ions and ethers: A poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride |
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| ASSEMBLING ETHYLENE, ALKYL, HYDRIDE, AND CO LIGANDS AT IRIDIUM |
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| A RU(II) ENYNYL COMPLEX MEDIATES THE CATALYTIC DIMERIZATION OF 1-ALKYNES TO Z-1,4-DISUBSTITUTED ENYNES |
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| AN ETA-4-BENZENE SPECIES MEDIATES ACETYLENE CYCLOTRIMERIZATION |
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| COUPLING OF 2 ETHYNE MOLECULES AT RHODIUM VERSUS COUPLING OF 2 RHODIUM ATOMS AT ETHYNE .2. IMPLICATIONS FOR THE REACTIVITY - CATALYTIC AND STOICHIOMETRIC FUNCTIONALIZATION REACTIONS OF ETHYNE |
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| Crystal Structure of the CIs Hydride Acetyl Complex [{N(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Rh(H)(COMe)]BPh<inf>4</inf>. One-Pot Synthesis of (σ-Acyl)metal Complexes from Aldehydes |
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| Coupling of Two Ethyne Molecules at Rhodium versus Coupling of Two Rhodium Atoms at Ethyne. 1. Electronic Control on the Interconversion of (μ-η<sup>2</sup>,η<sup>2</sup>-Ethyne)- and (μ-η<sup>1</sup>,η<sup>1</sup>-Ethyne)dirhodium Complexes |
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| Hydrochalcogenide and Hydride Hydrochalcogenide Derivatives of Rhodium |
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| CLASSICAL AND NONCLASSICAL POLYHYDRIDE RUTHENIUM(II) COMPLEXES STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 |
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| Reactivity of Pnicogen Chalcogenides with Metal-Ligand Fragments |
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| Synthesis and characterization of dirhodium complexes containing p-so, p-sh, and p-s<inf>2</inf>groups stabilized by the tripodal ligand ch<inf>3</inf>c(ch<inf>2</inf>pph<inf>2</inf>)<inf>3</inf> |
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| Reactions of the Trigonal-Bipyramidal Cobalt Hydride [{P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}COH] with 1-Alkynes. Synthesis and Reactivity of Acetylide, Alkenyl, and Vinylidene Complexes |
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| ELECTROCHEMISTRY AS A DIAGNOSTIC-TOOL TO DISCRIMINATE BETWEEN CLASSICAL M-(H)2 AND NONCLASSICAL M-(H2) STRUCTURES WITHIN A FAMILY OF DIHYDRIDE AND DIHYDROGEN METAL-COMPLEXES |
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| Hydrogen-Transfer Reactions of the Trihydride [(MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>)RhH<inf>3</inf>]: A Simple Route to Rhodium Cis Hydride η<sup>2</sup>-Alkene Complexes |
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| OXIDATION OF PRIMARY ALCOHOLS TO CARBOXYLIC-ACIDS MADE EASY AT IRIDIUM |
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| Distinct reaction pathways for some classical and nonclassical transition metal dihydrides |
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| ACTIVATION OF 1-ALKYNES AT TRIPODAL (POLYPHOSPHINE)RHODIUM SYSTEMS - REGIOSELECTIVE SYNTHESIS OF ENOL ESTERS FROM 1-ALKYNES AND CARBOXYLIC-ACIDS CATALYZED BY RHODIUM(I) MONOHYDRIDES |
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| Interaction of Monohydrido Complexes of Rhodium(I) with 1-Alkynes. Experimental Study on Deceptively Simple Reactions |
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| σ-Acetylide Complexes of Rhodium(I), Rhodium(II), and Rhodium(III). Correlation Between Electrochemical (E°’) and Spectroscopic (Δν(C≡C)) Parameters and dπ (Metal) → π<sup>*</sup> (Acetylide) Transfer |
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| Tripodal polyphosphine ligands in homogeneous catalysis. 1. hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with mec(ch<inf>2</inf>pph<inf>2</inf>)<inf>3</inf> |
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| Synthesis and characterization of gold adducts of [M(tppme)(P<inf>3</inf>)] [M = Co, Rh, or Ir; tppme = 1,1,1-tris(diphenylphosphinomethyl)ethane]. X-Ray crystal structures of [Au{M(tppme)(P<inf>3</inf>)}<inf>2</inf>]PF<inf>6</inf> (M = Co, Rh, or Ir) |
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| Synthesis, redox properties, and reactivity of a novel family of electron-rich vinylidene and vinylphosphonium complexes of rhodium(i) |
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| Synthesis and Structure of Dirhodium Compounds Featuring an End-On-Bridging Ditellurium |
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| ACTIVATION OF 1-ALKYNES AT 16-ELECTRON RHODIUM FRAGMENTS - SOME EXAMPLES OF THERMODYNAMICALLY FAVORED REARRANGEMENTS [M(PI-HC=CR)]-][M(H)(C=CR)] |
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| A HOMOGENEOUS IRON(II) SYSTEM CAPABLE OF SELECTIVELY CATALYZING THE REDUCTION OF TERMINAL ALKYNES TO ALKENES AND BUTA-1,3-DIENES |
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| Migration of hydrogen from metal to alkene promoted by dioxygen addition. Oxygen atom transfer from a cis-(alkyl)(η<sup>2</sup>-dioxygen) complex of rhodium to organic and inorganic substrates |
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| NUCLEOPHILIC PROPERTIES AND ELECTROCHEMISTRY OF 5-COORDINATE RHODIUM(I) SIGMA-CYANIDE COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF STABLE CIS HYDRIDE CYANIDE COMPLEXES OF RHODIUM(III) |
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| Cleavage of mixed tetrapnicogen trisulphide cage molecules by a cobalt(II)-ligand system. Crystal structure of the solid solution of [(tppme)Co(As<inf>2</inf>S)]BF<inf>4</inf> and [(tppme)Co(PAsS)]BF<inf>4</inf> |
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| Oxidative Addition/Reductive Elimination of Aldehydes and Ketones at Rhodium |
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| REDOX-INDUCED REVERSIBLE MIGRATION OF HYDROGEN FROM METAL TO ALKENE |
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| A STABLE ETA-2-H-2 COMPLEX OF COBALT - ROLE OF THE H-H INTERACTION IN HYDROGEN TRANSFER FROM METAL TO ALKENE |
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| Reactivity of Tetraphosphorus Trichalcogenides with Rhodium(I)- and Iridium(I)-Triphosphane Fragments. Synthesis and Characterization of Mixed-Metal and Unsubstituted-Main-Group-Element Cluster Compounds. Crystal and Molecular Tructures of [(triphos)M(P<inf>3</inf>X<inf>3</inf>)]·C<inf>6</inf>H<inf>6</inf> (M = Rh, X = S, Se; M = Ir, X = S) |
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| An exceptionally stable cis-(hydride)(η<sup>2</sup>-dihydrogen) complex of iron |
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| Rhodium Complexes with Tripodal Polyphosphines as Excellent Precursors to Systems for the Activation of H-H and C-H Bonds |
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| A SIMPLE, HIGH-YIELD SYNTHESIS OF TETRAPHOSPHORUS TRISELENIDE, P4SE3 |
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| Unprecedented Transformation of a Vinylldene Ligand. Synthesis and ESR Characterization of a Paramagnetic σ-Acetylide Complex of Rhodium(II) |
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| Homogeneous decarbonylation of ethyl formate at rhodium. Evidence for the formation of a cis-hydride(ethoxycarbonyl) intermediate through CH bond cleavage |
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| Activation of CH bonds in acetylene and terminal alkynes by rhodium(I) species. Crystal structure of cis-(ethynyl)hydride [(NP<inf>3</inf>)Rh(H)(CCH)]BPh<inf>4</inf>·1.5C<inf>4</inf>H<inf>8</inf>O (NP<inf>3</inf> = N(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>) |
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| Rhodium complexes with the tripodal triphosphine MeC(CH<inf>2</inf>PPh <inf>2</inf>)<inf>3</inf> as highly reactive systems for hydrogenation and hydroformylation of alkenes |
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| Diabetes mellitus and myocardial infarct in the elderly: role of the age factor,Diabete mellito ed infarto miocardico nell'anziano: il ruolo del fattore età. |
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| Polyhedron report number 19. Naked phosphorus atoms and units in transition-metal compounds |
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| Fast atom bombardment mass spectrometry of cationic complexes containing homo- and hetero-atomic cyclic units trihapto-bonded to the metal atom |
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| OXIDATIVE ADDITION REDUCTIVE ELIMINATION OF ALDEHYDES AND KETONES AT RHODIUM - SYNTHESIS AND CHARACTERIZATION OF CIS-HYDRIDO ACYL COMPLEXES OF RHODIUM(III) |
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| Hydrochalcogenide and hydride-hydrochalcogenide complexes of rhodium with the tripodal tetraphosphine pp<inf>3</inf> |
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| Synthesis and Structure of Compounds Containing Ditellurium Side‐on Bonded to Nickel Complex Fragments |
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| EVIDENCE FOR A MOLECULAR-HYDROGEN COMPLEX OF RHODIUM - SOME FACTORS AFFECTING CIS-DIHYDRIDE REVERSIBLE ETA-2-DIHYDROGEN EXCHANGE |
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| Fragmentation of realgar, As<inf>4</inf>S<inf>4</inf>, controlled by transition metalligand systems |
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| INSERTION OF PT(PPH3)2 INTO THE COORDINATED THIADIPHOSPHIRENE RING - STRUCTURE OF [LCO(P2SPT(PPH3)2)]BPH4, L = 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE |
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| Intramolecular, reversible C-H oxidative addition-reductive elimination at rhodium. Reaction of the intermediate with different types of C-H bonds and dihydrogen |
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| Alkyl, aryl and cis-dihydride complexes of iridium with the tripodal phosphine P(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf> as excellent precursors of active systems for the activation of hydrocarbon CH bonds |
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| Reactivity of arsenic selenides and telluride: Cobalt complexes containing the selena- or tellura-diarsirene cyclic units trihapto-bonded to the metal atom-crystal and molecular structures of [(triphos)Co(As<inf>2</inf>Se)](BF<inf>4</inf>)(C<inf>2</inf>H<inf>5</inf>OH) and [(triphos)Co(As<inf>2</inf>Te)](BF<inf>4</inf>(C<inf>6</inf>H<inf>6</inf>)<inf>0.5</inf> |
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| Intra- and Intermolecular Activation of sp<sup>2</sup>C-H Bonds at Rhodium(I) and Irldium(I) Metal Centers. X-ray Structure of the CIs a-Cyclooctadienyl Hydride [{N(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>j I rH (<r-C<inf>e</inf>H)]BPh<inf>4</inf>*CH<inf>3</inf>COCH<inf>3</inf> |
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| Electrophilic attack on unsubstituted phosphorus units in transition metal compounds: Synthesis and characterization of the methyltriphosphirene unit stabilized by transition metal-ligand fragments |
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| SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR METAL-COMPLEXES WITH THE AS2SE HETEROATOMIC INORGANIC GROUP AS BRIDGING UNIT - CRYSTAL AND MOLECULAR-STRUCTURE OF [(TRIPHOS)RH(AS2SE)RH(TRIPHOS)] (BPH4)2.2(CH3)2CO [TRIPHOS = 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE] |
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| Ditellurium as a bridging unit between metal-ligand systems. X-ray crystal structure of [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}Ni(Te <inf>2</inf>)Ni{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}]·2C <inf>4</inf>H<inf>8</inf>O |
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| Generation and Stabilization of the 3,3-Diphenyl-1,2,4-thiadlarsete Unit at a Transition Metal |
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| Reaction of cobalt and nickel moieties with the silylphosphane P<inf>7</inf>(SiMe<inf>3</inf>)<inf>3</inf> |
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| Phosphorus-phosphorus bond cleavage in the cage molecule P<inf>4</inf>S<inf>3</inf>: Synthesis and crystal structure of the trinuclear platinum complex [{Pt(μ-P<inf>4</inf>S<inf>3</inf>)(PPh<inf>3</inf>)} <inf>3</inf>]·C<inf>6</inf>H<inf>6</inf> |
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| Synthesis and Characterization of Dinuclear Metal Complexes with the P2S and As2S Heteroatomic Inorganic Rings as Bridging Units. Crystal and Molecular Structure of [(triphos)Rh(As2S)Rh(triphos)](BPh4)2.2(CH,)2CO [triphos = 1,1,1-Tris((diphenylphosphino) methyl)ethane] |
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| Gas-phase studies of phosphorus- and arsenic-chalcogenide cage molecules |
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| Synthesis and structural study of a cobalt complex with the diarsenic-sulfur cyclic unit as a trihapto ligand |
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| Insertion of the Pt(PPh<inf>3</inf>)<inf>2</inf> unit into inorganic triatomic rings coordinated to metal-ligand moieties |
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| The synthesis and characterization of cobalt complexes with diphosphorus-sulphur and -selenium cyclic units as trihapto ligands. X-Ray crystal structures of [Co{CMe(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}(P<inf>2</inf>X)]BF <inf>4</inf>·C<inf>6</inf>H<inf>6</inf> (X = S or Se) |
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| Cleavage of tetraarsenic trisulfide by nickle moieties |
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| Rhodium(III) and rhodium(I) complexes with tripod tetradentate ligands |
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| PHOSPHORUS AND ARSENIC CHALCOGENIDES AS REAGENTS TOWARD TRANSITION METAL-LIGAND SYSTEMS |
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| STRUCTURE OF (ETA-CYCLOTRIPHOSPHENYL)[1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE]NICKEL(II) TRIIODIDE 0.5-ACETONE SOLVATE, [NI(C41H39P3)(P3)]I3.0.5C3H6O |
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| PHOSPHORUS CHALCOGENIDES AS LIGANDS IN TRANSITION-METAL COMPLEXES |
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| Phosphorus Chalcogenides as Ligands in d<sup>10</sup> Metal Complexes |
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| Cleavage of P<inf>4</inf>S<inf>3</inf> and P<inf>4</inf>Se<inf>3</inf> cage molecules controlled by transition metal-ligand systems. X-ray crystal structure of [{MeC(CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>}-Rh(P <inf>3</inf>S<inf>3</inf>)]·C<inf>6</inf>H<inf>6</inf> |
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| The P<inf>4</inf>Se<inf>3</inf> cage molecule as a ligand. Crystal structure of [(N(CH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>)<inf>3</inf>) Ni(P<inf>4</inf>Se<inf>3</inf>]·2C<inf>6</inf>H<inf>6</inf> |
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| A cobalt complex containing the new trihapto-cyclic diphosphorus-sulphur ligand: Synthesis and x-ray crystal structure of [{MeC(CH<inf>2</inf>-PPh <inf>2</inf>)<inf>3</inf>}CoP<inf>2</inf>S]BF<inf>4</inf>·C <inf>6</inf>H<inf>6</inf> |
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| Octahedral nickel(II) complexes with the tripod ligand tris(2-dimethylarsionethyl)amine |
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| Synthesis and reactivity of novel cationic organonickel(II) compexes. X-ray structure of [bis(2-diphenylphosphinoethyl)phenylphosphinenickel-O-methylsulfinate]tetraphenylborate |
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